Abstract
We investigated the temperature dependence of growth mode in highly mismatched sputter-grown ZnO/Al2O3(0001) heteroepitaxial films using real-time synchrotron X-ray scattering. We find that the growth mode changes from 2 dimensional (2D) layer to 3D island in early growth stage with temperature (300∘C–500∘C). At around 400∘C, however, intermediate 2D platelets nucleate in early stage, act as nucleation cores of 3D islands and transform to misaligned state during further growth. The results of the strain evolution during growth suggest that the surface diffusion is a major factor in determining the growth mode in the strained ZnO/Al2O3(0001) heteroepitaxy.
Similar content being viewed by others
References
D.M. Bagnall, Y.F. Chen, Z. Zhu, T. Yao, M.Y. Shen, and T. Goto, Appl. Phys. Lett., 73, 1038 (1998).
Robert F. Service, Science, 276, 895 (1997).
Y. Chen, D.M. Bagnall, H.J. Koh, K.T. Park, K. Hiraga, Z.Z, and T. Yao, J. Appl. Phys., 84, 3912 (1998).
K. Ogata, K. Maejima, Sz. Fujita, and Sg. Fugita, J. Crystal Growth, 248, 25 (2003).
S.I. Park, T.S. Cho, S.J. Doh, J.L. Lee, and J.H. Je, Appl. Phys. Lett., 77, 349 (2001).
S.J. Doh, S.I. Park, T.S. Cho, and J.H. Je, J. Vac. Sci. Technol. A, 17, 3003 (1999).
J.H. Je, D.Y. Noh, H.K. Kim, and K.S. Liang, J. Appl. Phys., 81, 6126 (1997).
Y. Chen and J. Washbun, Phys. Rev. Lett., 77, 4046 (1996).
B. Chapman, Glow Discharge Processesi (John Wiley & Sons, 1980).
G. Mula, C. Adelmann, S. Moehl, J. Oullier, and B. Daudin, Phys. Rev. B, 64, 195406 (2001).
G. Wedler, J. Walz, T. Jesjedal, E. Chila, and R. Koch, Phys. Rev. Lett., 80, 2382 (1998).
C.W. Snyder, J.F. Mansfield, and B.G. Orr, Phys. Rev. B, 46, 9551 (1992).
I.V. Markov, Crystal Growth for Beginners (World Scientific, Singapore, 1995), Chap. 4.
W. Seifert, N. Carlsson, M. Miller, M.E. Pistol, L. Samuelson, and L.R. Wallenberg, Prog. Crystal Growth and Charact., 33, 423 (1996).
P.F. Miceli, C.J. Palmstrom, and K.W. Moyers, Appl. Phys. Lett., 58, 1602 (1991).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Kim, I.W., Kim, H.S., Doh, S.J. et al. Growth mode in strained ZnO films on Al2O3(0001) during sputtering. J Electroceram 17, 327–330 (2006). https://doi.org/10.1007/s10832-006-6288-2
Received:
Revised:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/s10832-006-6288-2