It is shown that the relations for determining a purely electronic transition from diffuse absorption or emission spectra, obtained under the assumption of microreversibility of optical vibronic transitions, follow from the quantum fluctuation theorem.
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Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 88, No. 5, pp. 812–814, September–October, 2021.
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Tolkachev, V.A. Determination of Pure Electronic Transition in Vibronic Spectra and Quantum Fluctuation Theorem. J Appl Spectrosc 88, 1040–1042 (2021). https://doi.org/10.1007/s10812-021-01276-3
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DOI: https://doi.org/10.1007/s10812-021-01276-3