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In situ Raman Spectroscopic Study of the Kinetics of the Chemical Dissolution of Ytterbium Oxide in YbCl3–KCl Melt

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Journal of Applied Spectroscopy Aims and scope

Using the Yb2O3–YbCl3–KCl oxide–chloride system as an example, an approach has been proposed and tested permitting a Raman spectral study of the kinetics of the dissolution of rare-earth metal oxides in molten salt media at high temperature. Evidence has been obtained for a chemical mechanism of the dissolution of ytterbium oxide in the YbCl3–KCl melt and the irreversibility of the chemical reaction taking place. The concentration of the ytterbium oxide reagent was found to decrease exponentially over time. Firstorder kinetics relative to Yb2O3 was established.

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References

  1. Q. Y. Zhang and X. Y. Huang, Prog. Mat. Sci., 55, 353–427 (2010); doi: https://doi.org/10.1016/j.pmatsci.2009.10.001.

    Article  Google Scholar 

  2. D. Xu, Y. Zhang, D. Zhang, and Sh. Yang, Cryst. Eng. Commun., 17, 1106–1114 (2015); doi: https://doi.org/10.1039/c4ce01970a.

    Article  Google Scholar 

  3. C. K. Gupta and N. Krishnamurthy, Extractive Metallurgy of Rare Earths, CRC Press (2005), pp. 31–32.

  4. G. E. Kodina, V. N. Kulakov, and I. N. Sheino, Saratov J. Med. Sci. Res., 10, 849–858 (2014).

    Google Scholar 

  5. X. Guan, U. B. Pal, Y. Jiang, and Sh. Su, J. Sustain. Metall., 2, 152–166 (2016); doi: https://doi.org/10.1007/s408310160044x.

    Article  Google Scholar 

  6. Y. Yan, X. Li, M. Zhang, H. Tang, W. Han, Y. Xue, and Z. Zhang, Energy Proc., 39, 408–414 (2013); https://doi.org/10.1016/j.egypro.2013.07.230.

    Article  Google Scholar 

  7. E. V. Nikolaeva, I. D. Zakiryanova, A. L. Bovet, and I. V. Korzun, J. Electrochem. Soc., 168, 016502 (2021); https://doi.org/10.1149/19457111/abd64a.

    Article  ADS  Google Scholar 

  8. I. D. Zakir'yanova, E. V. Nikolaeva, and I. V. Korzun, Mat. Sci. Forum, 989, 91–96 (2020); https://doi.org/10.4028/www.scientific.net/MSF.989.91.

    Article  Google Scholar 

  9. I. V. Korzun, E. V. Nikolaeva, and I. D. Zakir'yanova, J. Therm. Anal. Calorim., 144, 1343–1349 (2021); https://doi.org/10.1007/s10973020095582.

    Article  Google Scholar 

  10. X. Guo, J. Sietsma, and Y. Yang, in: Rare Earths Industry: Technological, Economic, and Environmental Implications, Elsevier (2015), pp. 223–234.

  11. I. D. Zakir'yanova, P. A. Arkhipov, and D. O. Zakir'yanov, J. Appl. Spectrosc., 82, 920–924 (2016); doi: 101007/s1081201602055.

  12. I. D. Zakir'yanova, J. Appl. Spectrosc., 81, No. 2, 301–304 (2014); https://doi.org/10.1007/s1081201499265.

    Article  ADS  Google Scholar 

  13. P. A. Arkhipov, I. D. Zakir'yanova, A. S. Kholkina, I. V. Korzun, and A. O. Khudorozhkova, J. Electrochem. Soc., 164, 5322–5326 (2017); doi: https://doi.org/10.1149/2.0461708jes.

    Article  Google Scholar 

  14. S. Park and J. Yun, J. Rare Earths, 38, 793–800 (2020); doi: https://doi.org/10.1016/j.jre.2019.06.008.

    Article  Google Scholar 

  15. E. Stefanidaki, G. M. Photiadis, C. G. Kontoyannis, A. F. Vik, and T. Østvold, J. Chem. Soc., Dalton Trans., 11, 2302–2307 (2002); 10.1039/B111563B.

  16. G. E. Revzin, in: Methods for Obtaining Chemical Reagents and Preparations [in Russian], Kurchatov Institute of Atomic Energy, Moscow (1967), pp. 124–129.

    Google Scholar 

  17. J. Sebastian and H. J. Seifert, Thermochim. Acta, 318, 29–37 (1998); doi: https://doi.org/10.1016/S00406031(98)003268.

    Article  Google Scholar 

  18. J. Yu, L. Cui, H. He, S. Yan, Y. Hu, and H. Wu, J. Rare Earths, 32, 1–4 (2014).

    Article  Google Scholar 

  19. Y. Iwadate, in: Molten Salts Chemistry. From Lab to Applications, Elsevier (2013), pp. 17–31; https://doi.org/10.1016/B9780123985385.000020.

  20. I. D. Zakiryanova and D. O. Zakiryanov, J. Mol. Liq., 318, 114054 (2020); https://doi.org/10.1016/j.molliq.2020.114054.

    Article  Google Scholar 

  21. X. Zhu, Sh. Sun, C. Liu, and G. Tu, J. Rare Earths, 36, 765–771 (2018); https://doi.org/10.1015/j.jre.2018.03.004.

    Article  Google Scholar 

  22. X. Guo, Z. Sun, J. Sietsma, B. Blanpain, M. Guo, and Y. Yang, Ind. Eng. Chem. Res., 57, 1380–1388 (2018); https://doi.org/10.1021/acs.iecr.7b04125.

    Article  Google Scholar 

  23. J. Brandmüller and H. Moser, Introduction to Raman Spectroscopy [Russian translation], Mir, Moscow (1964), pp. 465–486.

    Google Scholar 

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Authors and Affiliations

  1. Institute of High-Temperature Electrochemistry, Ural Branch of the Russian Academy of Science, Ekaterinburg, Russia

    I. D. Zakiryanova

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  1. I. D. Zakiryanova
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Correspondence to I. D. Zakiryanova.

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Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 88, No. 4, pp. 576–581, July–August, 2021.

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Zakiryanova, I.D. In situ Raman Spectroscopic Study of the Kinetics of the Chemical Dissolution of Ytterbium Oxide in YbCl3–KCl Melt. J Appl Spectrosc 88, 755–760 (2021). https://doi.org/10.1007/s10812-021-01236-x

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  • DOI: https://doi.org/10.1007/s10812-021-01236-x

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