Raman spectroscopy is proposed here for the study of forsterite–hydroxyapatite (FS–HA) composite coating on a stainless-steel substrate. However, in order to analyze the Raman spectrum accurately, noise and background removal is always required. A comparative study has been done for the correction of background. The waveletbased denoising of the signal was done using level 6 decomposition with sym4 wavelet and the thresholding method used was soft thresholding. In the present work, the effectiveness of the wavelet-based denoising method has been compared with Savitsky–Golay smoothing, quadratic regression, and the low-pass filter method. It is found that the wavelet-based denoising method works better as compared to other methods as it is able to smooth the signal and to increase the SNR while maintaining the peak intensity undistorted. Peaks are calculated for the different composition of the FS–HA composite. The variation of peak location in the processed Raman spectra suggests that the variation in concentration of FS and HA in the coating can be studied by using Raman spectroscopy.
Similar content being viewed by others
References
S.-I. Akimoto, Y. Matsui, and Y. Syono, in: The Physics and Chemistry of Minerals and Rocks, R. G. J. Strens Ed., Wiley Interscience, London (1976), pp. 327–363.
S. Ramesh, A. Yaghoubi, K. S. Lee, K. C. Chin, J. Purbolaksono, M. Hamdi, and M. A. Hassan, J. Mech. Behav. Biomed. Mater., 25, 63 (2013).
S. Ni, L. Chou, and J. Chang, Ceram. Int., 33, 83 (2007).
S. R. Levitt, P. H. Crayton, E. A. Monroe, and R. A. Condrate, J. Biomed. Mater. Res., 3, 683 (1969).
M. H. Fathi and A. Hanifi , Mater. Lett., 61, 3978 (2007).
Y.-M. Sung, J.-C. Lee, and J.-W. Yang, J. Cryst. Growth, 262, 467 (2004).
Y.-M. Sung and D.-H. Kim, J. Cryst. Growth, 254, 411 (2003).
M. A. Minnath, In Fundamental Biomaterials: Metals, Elsevier (2018), pp. 167–174.
I. Milošev, Pure Appl. Chem., 83, 309 (2010).
M. A. Ward and T. K. Georgiou, Polymers, 3, 1215 (2011).
I. Ibrahim, E. Sadiku, T. Jamiru, A. Hamam, and W. K. Kupolati, Curr. Trends Biomed. Eng. Biosci., 4, 9 (2017).
J. Chevalier and L. Gremillard, J. Eur. Ceram. Soc., 29, 1245 (2009).
A. Iftekhar, Standard Handbook of Biomedical Engineering and Design, McGraw-Hill Companies (2004).
L. Zhao, P. K. Chu, Y. Zhang, and Z. Wu, J. Biomed. Mater. Res., Part B: Appl. Biomater., 91, 470 (2009).
L. A. Thomson, F. C. Law, N. Rushton, and J. Franks, Biomaterials, 12, 37 (1991).
L. Tang, P. Thevenot, and W. Hu, Curr. Top. Med. Chem., 8, 270 (2008).
K. De Groot, J. G. C. Wolke, and J. A. Jansen, Proc. Inst. Mech. Eng., H: J. Eng. Med., 212, 137 (1998).
J. A. Davidson and P. Kovacs, US Patent 5, 169, 597 (December 1992).
P. S. Prakash, S. J. Pawar, and R. P. Tewari, Proc. Inst. Mech. Eng., L: J. Mater.: Des. Appl., 1464420717705151 (2017).
H. Khandelwal, G. Singh, K. Agrawal, S. Prakash, and R. D. Agarwal, Appl. Surf. Sci., 265, 30 (2013).
T. J. Vickers, R. E. Wambles Jr., and C. K. Mann, Appl. Spectrosc., 55, 389 (2001).
http://www.Chem.Uoa.Gr/Applets/Appletsmooth/Appl_smooth2. Html (Background on Ensemble Averaging) (2013).
A. Savitzky and M. J. Golay, Anal. Chem., 36, 1627 (1964).
F. Ehrentreich and L. Sümmchen, Anal. Chem., 73, 4364 (2001).
H. Chen, W. Xu, N. Broderick, and J. Han, J. Raman Spectrosc., 49, 1529 (2018).
K. F. McCarty and D. R. Boehme, J. Solid. State Chem., 79, 19 (1989).
J. E. Maslar, W. S. Hurst, W. J. Bowers Jr., and J. H. Hendricks, Corrosion, 58, 739 (2002).
B. Mihailova, B. Kolev, C. Balarew, E. Dyulgerova, and L. Konstantinov, J. Mater. Sci., 36, 4291 (2001).
D. C. O'shea, M. L. Bartlett, and R. A. Young, Arch. Oral Biol., 19, 995 (1974).
W. P. Griffith, J. Chem. Soc. A: Inorg., Phys., Theor., 286 (1970).
G. R. Sauer, W. B. Zunic, J. R. Durig, and R. E. Wuthier, Calcified Tissue Int., 54, 414 (1994).
B. O. Fowler, M. Markovic, and W. E. Brown, Chem. Mater., 5, 1417 (1993).
H. Tsuda and J. Arends, J. Dent. Res., 72, 1609 (1993).
Author information
Authors and Affiliations
Corresponding authors
Additional information
Abstract of article is published in Zhurnal Prikladnoi Spektroskopii, Vol. 87, No. 3, p. 507, May–June, 2020.
Rights and permissions
About this article
Cite this article
Prakash, P.S., Sharan, T.S., Pawar, S.J. et al. Wavelet-Based Noise Removal from Raman Signal to Study PLD Coated Forsterite–Hydroxyapatite Thin Film on Stainless Steel 316l Substrate. J Appl Spectrosc 87, 545–552 (2020). https://doi.org/10.1007/s10812-020-01037-8
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10812-020-01037-8