The optical absorption spectra and spin-Hamiltonian parameters (g factors g||, g⊥, and hyperfine structure constants A||, A⊥ ) of vanadyl in zinc phosphate glass are investigated, using the high-order perturbation formulas for a 3d1 ion in tetragonally compressed octahedra. In the calculations, the required crystal-field parameters are estimated from the superposition model, and the optical absorption bands and spin-Hamiltonian parameters are linked with the tetragonal distortion (characterized by ΔR = R⊥ – R||, where R⊥ and R|| denote the bond lengths perpendicular and parallel to the C4 axis). Based on the calculations, the tetragonal distortion ΔR (≈1.795 Å) was obtained, and negative signs of the hyperfine structure constants A|| and A⊥ are suggested.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
K. Srinivasulu, I. Omkaram, H. Obeid, A. S. Kumar, and J. L. Rao, Physica B, 407, 4741–4748 (2012).
R. V. S. S. N. Ravikumar, R. Komatsu, K. Ikeda, A. V. Chandrasekhar, B. J. Reddyc, Y. P. Reddy, and P. S. Rao, Solid State Commun., 126, 251–253 (2003).
N. G. Boetti, J. Lousteau, E. Ceci-Ginistrelli, E. Bertone, F. Geobaldo, and D. Milanese, J. Alloys Compd., 657, 678–683 (2016).
K. Srinivasulu, I. Omkaram, H. Obeid, A. S. Kumar, and J. L. Rao, J. Phys. Chem. A, 116, 3547–3555 (2012).
S. C. Colak and E. Aral, J. Alloys Compd., 509, 4935–4939 (2011).
R. Lakshmikantha, N. H. Ayachit, and R. V. Anavekar, J. Phys. Chem. Solids, 75, 168–173 (2014).
B. Natarajan, S. Deepa, S. Mithira, R. V. S. S. N. Ravikumar, and P. S. Rao, Phys. Scr., 76, 253–258 (2007).
C. C Ding, S. Y. Wu, L. Peng, L. N. Wu, Z. H. Zhang, Q. S. Zhu, M. H. Wu, and B. H. Teng, J. Non-Cryst. Solids, 481, 103–109 (2018).
R. Kripal and M. Maurya, Physica B, 404, 1532–1537 (2009).
M. Farouk, A. Samir, and M. El Okr, Physica B, 530, 43–48 (2018).
S. Mukherjee and A. K. Pal, J. Phys.: Condens. Matter, 20, 255202 (2008).
B. Karabulut and A. Tufan, Spectrochim. Acta A, 65, 742–748 (2006).
B. Srinivas, A. Hameed, G. Ramadevudu, M. N. Chary, and Md. Shareefuddin, J. Phys. Chem. Solids, 129, 22–30 (2019).
O. Cozar, D. A. Magdas, and I. Ardelean, J. Optoelectron, Adv. Mater., 9, 1730–1735 (2007).
P. S. Rao, P. M. V. Teja, A. R. Babu, Ch. Rajyasree, and D. K. Rao, J. Non-Cryst. Solids, 358, 3372–3381 (2012).
B. Srinivas, A. Hameed, R. V. Kumar, M. C. Narasimha, and Md. Shareefuddin, Philos. Mag., 98, 1625–1640 (2018).
V. Sreenivasulu, G. Upender, V. C. Mouli, and M. Prasad, Spectrochim. Acta A, 148, 215–222 (2015).
R. V. S. S. N. Ravikumar, B. C. Jamalaiah, A. V. Chandrasekhar, B. J. Reddy, Y. P. Reddy, and P. S. Rao, J. Alloys Compd., 287, 84–86 (1999).
A. Abragam and B. Bleaney, Electron Paramagnetic Resonance of Transition Ions, Oxford University Press, London (1970).
C. C. Ding, S. Y. Wu, L. N. Wu, L. J. Zhang, L. Peng, M. H. Wu, and B. H. Teng, J. Phys. Chem. Solids, 113, 102–107 (2018).
D. J. Newman and B. Ng, Rep. Prog. Phys., 52, 699–763 (1989).
M. Q. Kuang, S. Y. Wu, G. L. Li, and X. F. Hu, Mol. Phys., 113, 698–702 (2015).
H. M. Zhang, S. Y. Wu, M. Q. Kuang, and Z. H. Zhang, J. Phys. Chem. Solids, 73, 846–850 (2012).
M. N. Li, Z. H. Zhang, and S. Y. Wu, Z. Naturforsch. A, 72, 1139–1143 (2017).
R. M. Krishna, J. J. Andre, V. P. Seth, S. Khasa, and S. K. Gupta, Mater. Res. Bull., 34, 1089–1097 (1999).
C. Y. Li and X. M. Zheng, Acta Phys. Pol. A, 125, 73–76 (2014).
S. Y. Wu, X. Y. Gao, and H. N. Dong, J. Magn. Magn. Mater., 301, 67–73 (2006).
B. R. McGarvey, J. Phys. Chem., 71, 51–66 (1967).
E. Clementi, D. L. Raimondi, and W. P. Reinhardt, J. Chem. Phys., 47, 1300–1307 (1967).
E. Clementi and D. L. Raimondi, J. Chem. Phys., 38, 2686–2689 (1963).
J. S. Griffith, The Theory of Transition-Metal Ions, Cambridge University Press, London (1964).
E. K. Hodgson and I. Fridovich, Biophys. Biochem. Res. Commun., 54, 270–274 (1973).
H. M. Zhang, W. B. Xiao, and X. Wan, Physica B, 449, 225–228 (2014).
W. L. Feng, Philos. Mag., 89, 1391–1394 (2009).
R. Muncaster and S. Parke, J. Non-Cryst. Solids, 24, 399–412 (1977).
E. Kalfaoğlu and B. Karabulut, J. Magn. Magn. Mater., 324, 1593–1595 (2012).
Author information
Authors and Affiliations
Corresponding author
Additional information
Published in Zhurnal Prikladnoi Spektroskopii, Vol. 87, No. 3, pp. 413–417, May–June, 2020.
Rights and permissions
About this article
Cite this article
Feng, CD., Huang, HX., Xiao, WB. et al. Investigation of the Optical Spectra and Spin-Hamiltonian Parameters for Vanadyl in Zinc Phosphate Glass. J Appl Spectrosc 87, 452–456 (2020). https://doi.org/10.1007/s10812-020-01022-1
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10812-020-01022-1