Skip to main content
SpringerLink
Log in

Photoluminescence Spectra of the 580-nm Center in Irradiated Diamonds

  • Published:
Journal of Applied Spectroscopy Aims and scope

The formation mechanisms of the zero-phonon line optical center at 580 nm (H19 center) in photoluminescence spectra of irradiated natural diamonds and those deposited from the vapor phase were studied after their high-temperature vacuum annealing. The photoluminescence band intensity of the H19 center was shown to increase exponentially as the annealing temperature increased. Temperature dependences of photoluminescence spectra and local mechanical stress effects on the position and full width at half-height of the 580-nm zero-phonon line optical peak led to the conclusion that the H19 optical center was a complex intrinsic vacancy defect.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. A. Sipahigil, R. E. Evans, D. D. Sukachev, M. J. Burek, J. Borregaard, M. K. Bhaskar, C. T. Nguyen, J. L. Pacheco, H. A. Atikian, C. Meuwly, R. M. Camacho, F. Jelezko, E. Bielejec, H. Park, M. Loncar, and M. D. Lukin, Science, 354, No. 6314, 847–850 (2016).

    Article  ADS  Google Scholar 

  2. S. Johnson, P. R. Dolan, and J. M. Smith, Prog. Quant. Electron., 55, 129–165 (2017).

    Article  ADS  Google Scholar 

  3. E. Ekimov, M. V. Kondrin, V. S. Krivobok, A. A. Khomich, I. I. Vlasov, R. A. Khmelnitskiy, T. Iwasaki, and M. Hatano, Diamond Relat. Mater., 93, 75–83 (2019).

    Article  ADS  Google Scholar 

  4. T. Luhmann, N. Raatz, R. John, M. Lesik, J. Rodiger, M. Portail, D. Wildanger, F. Kleissler, K. Nordlund, A. Zaitsev, J.-F. Roch, A. Tallaire, J. Meijer, and S. Pezzagna, J. Phys. D: Appl. Phys., 51, No. 48, 483002 (2018).

    Article  Google Scholar 

  5. B. Dischler, Handbook of Spectral Lines in Diamond. Vol. 1. Tables and Interpretations, New York, Springer (2012), pp. 14–64.

    Book  Google Scholar 

  6. A. V. Khomich, R. A. Khmel′nitskii, N. A. Poklonskii, N. M. Lapchuk, A. A. Khomich, V. A. Dravin, O. N. Poklonskaya, E. E. Ashkinazi, I. I. Vlasov, E. V. Zavedeev, and V. G. Ral′chenko, Zh. Prikl. Spektrosk., 79, No. 4, 615–624 (2012) [A. V. Khomich, R. A. Khmelnitsky, N. A. Poklonski, N. M. Lapchuk, A. A. Khomich, V. A. Dravin, O. N. Poklonskaya, E. E. Ashkinazi, I. I. Vlasov, E. V. Zavedeev, and V. G. Ralchenko, J. Appl. Spectrosc., 79, No. 4, 600–609 (2012)].

  7. A. A. Khomich, V. G. Ral′chenko, A. V. Khomich, I. I. Vlasov, R. A. Khmel′nitskii, and A. E. Kar′kin, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 56, No. 5, 27–31 (2013).

    Google Scholar 

  8. A. V. Khomich, A. E. Kar′kin, V. G. Ral′chenko, I. I. Vlasov, A. A. Khomich, N. M. Lapchuk, O. N. Poklonskaya, R. A. Khmel′nitskii, A. A. Averin, and A. A. Shiryaev, in: Proc. 9th Int. Confrence "Interaction of Radiation with Matter" [in Russian], September 20–22, 2011, Minsk, Izd. Tsentr BGU, Minsk (2011), pp. 180–182.

    Google Scholar 

  9. C. D. Clark, R. W. Ditchburn, and H. B. Dyer, Proc. R. Soc. London, Ser. A, 234, 363–381 (1956).

    Article  ADS  Google Scholar 

  10. A. M. Zaitsev, Optical Properties of Diamond. A Data Handbook, Springer, Berlin (2001), p. 262.

    Book  Google Scholar 

  11. A. A. Khomich, A. A. Averin, O. N. Poklonskaya, A. I. Kovalev, M. V. Kozlova, R. A. Khmel′nitskii, V. G. Ral′chenko, N. A. Poklonskii, and A. V. Khomich, in: Proc. 12th Int. Conf. "Interaction of Radiation with Matter" [in Russian], September 19–22, 2017, Minsk, Izd. Tsentr BGU, Minsk (2017), pp. 75–77.

    Google Scholar 

  12. J. Forneris, P. Traina, D. G. Monticone, G. Amato, L. Boarino, G. Brida, I. P. Degiovanni, E. Enrico, E. Moreva, V. Grilj, N. Skukan, M. Jaksic, M. Genovese, and P. Olivero, Sci. Rep., 5, 15901 (2015).

    Article  ADS  Google Scholar 

  13. J. Forneris, S. D. Tchernij, A. Tengattini, E. Enrico, V. Grilj, N. Skukan, G. Amato, L. Boarino, M. Jaksic, and P. Olivero, Carbon, 113, 76–86 (2017).

    Article  Google Scholar 

  14. K. Wang, J. Steeds, and Z. Li, Diamond Relat. Mater., 25, 29–33 (2012).

    Article  ADS  Google Scholar 

  15. J. W. Steeds, Nucl. Instrum. Methods Phys. Res., Sect. B, 269, 1702–1706 (2011).

    Article  ADS  Google Scholar 

  16. S. V. Nistor, M. Stefan, V. Ralchenko, A. Khomich, and D. Schoemaker, J. Appl. Phys., 87, 8741–8746 (2000).

    Article  ADS  Google Scholar 

  17. A. V. Khomich, R. A. Khmel′nitskii, X. J. Hu, A. A. Khomich, A. F. Popovich, I. I. Vlasov, V. A. Dravin, Y. G. Chen, A. E. Kar′kin, and V. G. Ral′chenko, Zh. Prikl. Spektrosk., 80, No. 5, 719–726 (2013) [A. V. Khomich, R. A. Khmelnitskii, X. J. Hu, A. A. Khomich, A. F. Popovich, I. I. Vlasov, V. A. Dravin, Y. G. Chen, A. E. Karkin, and V. G. Ralchenko, J. Appl. Spectrosc., 80, 707–714 (2013)].

  18. A. Bolshakov, V. Ralchenko, V. Sedov, A. Khomich, I. Vlasov, A. Khomich, N. Trofimov, V. Krivobok, S. Nikolaev, R. Khmelnitskii, and V. Saraykin, Phys. Status Solidi A, 212, 2525–2532 (2015).

    Article  ADS  Google Scholar 

  19. А. V. Khomich, V. G. Ralchenko, A. V. Vlasov, R. A. Khmelnitskiy, I. I. Vlasov, and V. I. Konov, Diamond Relat. Mater., 10, 546–551 (2001).

    Article  ADS  Google Scholar 

  20. A. A. Gippius, A. M. Zaitsev, and V. S. Vavilov, Fiz. Tekh. Poluprovodn., 16, 404–411 (1982) [A. A. Gippius, A. M. Zaitsev, and V. S. Vavilov, Sov. Phys. Semicond., 16, 256–261 (1982)].

  21. А. А. Gippius, R. A. Khmelnitskiy, V. A. Dravin, and A. V. Khomich, Diamond Relat. Mater., 12, 538–541 (2003).

    Article  ADS  Google Scholar 

  22. K. Iakoubovskii, G. J. Adriaenssens, and M. Nesladek, J. Phys.: Condens. Matter, 12, 189–199 (2000).

    ADS  Google Scholar 

  23. R. U. A. Khan, P. M. Martineau, B. L. Cann, M. E. Newton, and D. J. Twitchen, J. Phys.: Condens. Matter, 21, 364214 (2009).

    Google Scholar 

  24. S. Onoda, K. Tatsumi, M. Haruyama, T. Teraji, J. Isoya, W. Kada, T. Ohshima, and O. Hanaizumi, Phys. Status Solidi A, 214, 1700160 (2017).

    Article  ADS  Google Scholar 

  25. G. Davies and A. T. Collins, Diamond Relat. Mater., 2, 80–86 (1993).

    Article  ADS  Google Scholar 

  26. E. Anastassakis, J. Appl. Phys., 86, 249–258 (1999).

    Article  ADS  Google Scholar 

  27. I. I. Vlasov, V. G. Ralchenko, E. D. Obraztsova, A. A. Smolin, and V. I. Konov, Appl. Phys. Lett., 71, 1789–1791 (1997).

    Article  ADS  Google Scholar 

  28. L. Nistor, V. Ralchenko, I. Vlasov, A. Khomich, R. Khmelnitskiy, P. Potapov, and J. Van Landuyt, Phys. Status Solidi A, 186, 207–214 (2001).

    Article  ADS  Google Scholar 

  29. V. Ralchenko, L. Nistor, E. Pleuler, A. Khomich, I. Vlasov, and R. Khmelnitskii, Diamond Relat. Mater., 12, 1964–1970 (2003).

    Article  ADS  Google Scholar 

  30. A. A. Khomich, A. N. Dzeraviaha, O. N. Poklonskaya, A. V. Khomich, R. A. Khmelnitsky, N. A. Poklonski, and V. G. Ralchenko, J. Phys.: Conf. Ser., 1135, 012019 (2018).

    Google Scholar 

  31. K. K. Rebane, Impurity Spectra of Solids: Elementary Theory of Vibrational Structure, Plenum Press, New York, London (1970), p. 45.

    Google Scholar 

  32. V. Hizhnyakov, H. Kaasik, and I. Sildos, Phys. Status Solidi B, 234, 644–653 (2002).

    Article  ADS  Google Scholar 

  33. M. W. Doherty, V. M. Acosta, A. Jarmola, M. S. J. Barson, N. B. Manson, D. Budker, and L. C. L. Hollenberg, Phys. Rev. B: Condens. Matter Mater. Phys., 90, 041201(R) (2014).

    Article  ADS  Google Scholar 

  34. G. Davies, in: CVD Diamond for Electronic Devices and Sensors, R. S. Sussmann (Ed.), Wiley, Chichester (2009), pp. 3–28.

    Google Scholar 

  35. A. M. Zaitsev, Phys. Rev. B: Condens. Matter Mater. Phys., 61, 12909–12922 (2000).

    Article  ADS  Google Scholar 

  36. W. Windl, P. Pavone, K. Karch, O. Schutt, D. Strauch, P. Giannozzi, and S. Baroni, Phys. Rev. B: Condens. Matter Mater. Phys., 48, 3164–3170 (1993).

    Article  ADS  Google Scholar 

  37. P. Nemeth, L. A. J. Garvie, T. Aoki, N. Dubrovinskaia, L. Dubrovinsky, and P. R. Buseck, Nat. Commun., 5, 5447 (2014).

    Article  ADS  Google Scholar 

  38. S. M. Pimenov, A. A. Khomich, I. I. Vlasov, E. V. Zavedeev, A. V. Khomich, B. Neuenschwander, B. Jaggi, and V. Romano, Appl. Phys. A: Mater. Sci. Process., 116, 545–554 (2014).

    Article  ADS  Google Scholar 

  39. O. N. Poklonskaya, S. A. Vyrko, A. A. Khomich, A. A. Averin, A. V. Khomich, R. A. Khmel′nitskii, and N. A. Poklonskii, Zh. Prikl. Spektrosk., 81, No. 6, 879–887 (2014) [O. N. Poklonskaya, S. A. Vyrko, A. A. Khomich, A. A. Averin, A. V. Khomich, R. A. Khmelnitsky, and N. A. Poklonski, J. Appl. Spectrosc., 81, No. 6, 969–977 (2015)].

  40. R. Sandstrom, L. Ke, A. Martin, Z. Wang, M. Kianinia, B. Green, W. Gao, and I. Aharonovich, Opt. Commun., 411, 182–186 (2018).

    Article  ADS  Google Scholar 

  41. V. D. Tkachev, A. M. Zaitsev, and V. V. Tkachev, Phys. Status Solidi B, 129, 129–133 (1985).

    Article  ADS  Google Scholar 

  42. M. Wang, G. Shi, J. C. C. Yuan, W. Han, and Q. Bai, J. Spectrosc., 2018, 8153941 (2018).

    Article  Google Scholar 

  43. Diamond (C), EPR spectra W1–W44, in: Impurities and Defects in Group IV Elements, IV–IV and III–V Compounds. Part a: Group IV Elements, O. Madelung, U. Rossler, and M. Schulz (Eds.), Springer, Berlin (2002), pp. 1–22.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. V. A. Kotelnikov Institute of Radio Engineering and Electronics, Fryazino Branch, Russian Academy of Sciences, 1 Vvedenskogo Sq., Fryazino, 141190, Moscow Region, Russia

    A. A. Khomich & A. V. Khomich

  2. P. N. Lebedev Physical Institute, Russian Academy of Sciences, Moscow, 117924, Russia

    R. A. Khmelnitskii

  3. Belarusian State University, 220030, Minsk, Belarus

    O. N. Poklonskaya & N. A. Poklonskii

  4. A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, 119071, Russia

    A. A. Averin

  5. A. M. Prokhorov General Physics Institute, Russian Academy of Sciences, Moscow, 117942, Russia

    S. N. Bokova-Sirosh & V. G. Ralchenko

  6. Harbin Institute of Technology, Harbin, 150001, China

    V. G. Ralchenko

Authors
  1. A. A. Khomich
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. R. A. Khmelnitskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. O. N. Poklonskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. A. Averin
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. S. N. Bokova-Sirosh
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. N. A. Poklonskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. V. G. Ralchenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. A. V. Khomich
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. A. Khomich.

Additional information

Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 86, No. 4, pp. 539–548, July–August, 2019.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Khomich, A.A., Khmelnitskii, R.A., Poklonskaya, O.N. et al. Photoluminescence Spectra of the 580-nm Center in Irradiated Diamonds. J Appl Spectrosc 86, 597–605 (2019). https://doi.org/10.1007/s10812-019-00865-7

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10812-019-00865-7

Keywords

Search

Navigation