Skip to main content
SpringerLink
Log in

Spectral-Luminescent Properties of Alkoxysilane–Metallophthalocyanine Conjugates Covalently Bonded to the Polymeric Chains of Silicate Gel Materials

  • Published:
Journal of Applied Spectroscopy Aims and scope

Conjugates of metal hydroxyl phthalocyanines (М(ОН)nРс; М = Si, Ge, Al, Ga) with 3-aminopropyltriethoxysilane (APTEOS) are synthesized. By means of the sol-gel method, polymeric silicate gel materials doped with the (APTEOS)n–М(ОН)nРс conjugates are prepared: the latter form structural links in the composition of the copolymer with the siloxane fragments of the polymeric chains (in the case of n = 2) or are ″grafted″ to such chains in the form of side substituents (n = 1). It is shown by spectral-luminescent and kinetic spectroscopy methods that the (APTEOS)n–М(ОН)nРс conjugates, on the introduction into a silicate gel material, retain their molecular structure and the photophysical characteristics of MPc in the monomeric form. The obtained macromolecular substances are promising as monomeric dopants in new functional materials for optics and quantum electronics.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. C. C. Leznoff and A. B. P. Lever (Eds.), Phthalocyanines: Properties and Applications, 1–4, New York, VCH (1989–1996).

  2. A.W. Snow, in: K. M. Kadish, K. M. Smith, and R. Guilard (Eds.), The Porphyrin Handbook, 17, Academic Press, San Diego (2003), pp. 129–176.

    Chapter  Google Scholar 

  3. A. S. Akopov, B. D. Berezin, V. N. Klyuev, and A. A. Solovyov, Zh. Neorg. Khim., 17, 981–984 (1972).

    Google Scholar 

  4. E. Orthmann and G. Wegner, Makromol. Chem. Rapid Commun., 7, 243–247 (1986).

    Article  Google Scholar 

  5. C. W. Dirk, T. Inabe, K. F. Schoch, Jr., and T. J. Marks, J. Am. Chem. Soc., 105, 1539–1550 (1983).

    Article  Google Scholar 

  6. D. R. Uhlmann and G. Teowee, J. Sol-Gel Sci. Technol., 13, 153–162 (1998).

    Article  Google Scholar 

  7. S. M. Arabei, T. A. Pavich, and K. N. Solovyov, J. Porph. Phtaloc., 17, 636–648 (2013).

    Article  Google Scholar 

  8. T. A. Pavich, S. M. Arabei, and K. N. Solovyov, Zh. Prikl. Spektrosk., 85, 1–8 (2018) [T. A. Pavich, S. M. Arabei, and K. N. Solovyov, J. Appl. Spectrosc., 85, 1–8 (2018)].

  9. H. Xia, M. Nogami, T. Hayakawa, and D. Imaizumi, J. Mater. Sci. Lett., 18, 1837–1839 (1999).

    Article  Google Scholar 

  10. H. Xia, B. Pu, Y. Zhang, J. Zhang, J. Fang, and C. Wang, Chin. Sci. Bull., 45, 2198–2203 (2000).

    Article  Google Scholar 

  11. B. D. Berezin and A. S. Akopov, Zh. Obshch. Khim., 44, 1089–1093 (1974).

    Google Scholar 

  12. A. R. Kane, J. F. Sullivan, D. H. Kenny, and M. E. Kenney, Inorg. Chem., 9, 1445–1448 (1970).

    Article  Google Scholar 

  13. K. Ishii, Y. Hirose, H. Fujitsuka, O. Ito, and N. Kobayashi, J. Am. Chem. Soc., 123, 702–708 (2001).

    Article  Google Scholar 

  14. A. T. Gradyushko, A. N. Sevchenko, K. N. Solovyov, and M. P. Tsvirko, Photochem. Photobiol., 11, 387–400 (1970).

    Article  Google Scholar 

  15. A. Gordon and R. Ford, The Chemist′s Companion [Russian translation], Mir, Moscow (1976), pp. 95–101.

Download references

Author information

Authors and Affiliations

  1. B. I. Stepanov Institute of Physics of the National Academy of Sciences of Belarus, Minsk, Belarus

    T. A. Pavich & K. N. Solovyov

  2. Belarusian State Agrarian and Technical University, 99 Nezavisimost′ Ave., 220023, Minsk, Belarus

    S. M. Arabei

Authors
  1. T. A. Pavich
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. M. Arabei
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. K. N. Solovyov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to S. M. Arabei.

Additional information

Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 85, No. 4, pp. 584–591, July–August, 2018.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Pavich, T.A., Arabei, S.M. & Solovyov, K.N. Spectral-Luminescent Properties of Alkoxysilane–Metallophthalocyanine Conjugates Covalently Bonded to the Polymeric Chains of Silicate Gel Materials. J Appl Spectrosc 85, 638–644 (2018). https://doi.org/10.1007/s10812-018-0698-1

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10812-018-0698-1

Keywords

Search

Navigation