The state of water in hydrogels of sodium carboxymethylcellulose and bentonite was studied by low-temperature PMR spectroscopy. Polymer macromolecules interacted actively with the bentonite. The thermodynamic parameters of layers of strongly and weakly bound water and the interphase energy of water in the hydrogels were determined.
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V. N. Pavlyuchenko and S. S. Ivanchev, Vysokomol. Soedin., Ser. A, 51, No. 7, 1075–1095 (2009) [V. N. Pavlyuchenko and S. S. Ivanchev, Polym. Sci., Ser. A, 51, No. 7, 743–760 (2009)].
S. K. H. Gulrez, S. Al-Assaf, and G. O. Phillips, Progress in Molecular and Environmental Bioengineering — From Analysis and Modeling to Technology Applications, InTech (2011), pp. 118–142.
V. J. McBrierty, S. J. Martin, and F. E. Karasz, J. Mol. Liq., 80, Nos. 2–3, 179–205 (1999).
M. A. Bag and L. M. Valenzuela, Int. J. Mol. Sci., 18, No. 8, 1422–1453 (2017); doi:https://doi.org/10.3390/ijms18081422.
V. V. Goncharuk, L. V. Dubrovina, and E. V. Makarova, Khim. Tekhnol. Vody, 39, No. 5, 459–469 (2017) [V. V. Goncharuk, L. V. Dubrovina, and E. V. Makarova, J. Water Chem. Technol., 39, 257–262 (2017)].
M. I. Shumskaite and V. N. Glinskikh, Geol. Geofi z., 57, No. 10, 1911–1918 (2016) [M. I. Shumskayte and V. N. Glinskikh, Russ. Geol. Geophys., 57, 1509–1514 (2016)].
G. R. Coates, Xiao Lizhi, and M. G. Prammer, NMR Logging, Principles & Applications, Halliburton Energy Services Publishing, Houston (2000).
Yu. I. Tarasevich, Khim. Tekhnol. Vody, 35, No. 3, 177–187 (2013).
V. M. Gun′ko, V. V. Turov, V. M. Bogatyrev, V. I. Zarko, R. Leboda, E. V. Goncharuk, A. A. Novza, A. V. Turov, and A. A. Chuiko, Adv. Colloid Interface Sci., 118, Nos. 1–3, 125–172 (2005).
V. M. Gun′ko, V. V. Turov, and P. P. Gorbik, Water at Interfacial Boundaries [in Russian], Naukova Dumka, Kiev (2009).
V. M. Gun′ko and V. V. Turov, Nuclear Magnetic Resonance Studies of Interfacial Phenomena, Taylor & Francis, New York (2013).
J. C. Hindman, J. Chem. Phys., 44, 4582–4592 (1966).
O. V. Petrov and I. Furo, Prog. Nucl. Magn. Reson. Spectrosc., 54, 97–122 (2009).
D. W. Aksnes and L. Kimtys, Solid State Nucl. Magn. Reson., 25, 146–163 (2004).
Yu. G. Frolov, Course in Colloid Chemistry. Surface Phenomena and Disperse Systems [in Russian], Khimiya, Moscow (1982).
V. P. Glushko (Ed.), Thermodynamic Properties of Pure Compounds [in Russian], Nauka, Moscow (1978).
C. G. Lopez, S. E. Rogers, R. H. Colby, P. Graham, and J. T. Cabral, J. Polym. Sci., Part B: Polym. Phys., 53, No. 7, 492–501 (2015).
G. A. Petropavlovskii, Hydrophilic Partially Substituted Cellulose Ethers and Their Modifi cation by Chemical Cross-Linking [in Russian], Nauka, Leningrad (1988).
E. V. Sobotovich, G. P. Zadvernyuk, V. M. Kadoshnikov, B. P. Zlobenko, I. P. Pisans′ka, and Yu. G. Fedorenko, Mineral. Zh., 30, No. 4, 32–40 (2008).
V. I. Osipov, V. N Sokolov, and N. A. Rumyantseva, Microstructure of Clay Rocks [in Russian], Nedra, Moscow (1989).
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Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 85, No. 4, pp. 538–544, July–August, 2018.
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Goncharuk, V.V., Dubrovina, L.V., Makarova, E.V. et al. Bound Water in Hydrogels of Carboxymethylcellulose and Bentonite. J Appl Spectrosc 85, 594–599 (2018). https://doi.org/10.1007/s10812-018-0691-8
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DOI: https://doi.org/10.1007/s10812-018-0691-8