Journal of Applied Spectroscopy

, Volume 85, Issue 2, pp 260–266 | Cite as

Influence of γ-Irradiation on the Optical Properties of the Polyimide–YBa2Cu3O6.7 System

  • A. D. MuradovEmail author
  • N. E. Korobova
  • A. A. Kyrykbaeva
  • G. Sh. Yar-Mukhamedova
  • K. M. Mukashev

Influence of γ-irradiation on the optical properties of a polyimide film and its polymer compositions with fillers of a dispersed powder of a high-temperature superconductor ҮBa2Cu3O6.7 (YBaCuO) with concentrations of 0.05, 0.10, and 0.50 wt.% was studied. It was established that γ-irradiation with a dose up to 600 kGy does not affect the transparency of polyimide films in the visible region of the spectrum. However, at irradiation doses of 250 and 600 kGy, a weakly expressed fine structure appears in the spectra of polyimide films in the range of 220–300 nm due to the contribution of the resulting diene structures to the optical transmission and the increased content of oxygen atoms. The YBaCuO filler and γ-irradiation cause the polyimide transition from the amorphous state to the crystalline state, which is manifested in a sharp change in the spectrum in the range of ~2.3–3.9 eV. A significant increase in the extinction coefficient was found in the composite containing 0.50 wt.% of the filler that is associated with an increase in the radius of action of structurally active fillers on the macromolecules of the matrix.


polyimide composite material filler high-temperature superconductor optical properties gamma irradiation dose 


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© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  • A. D. Muradov
    • 1
    Email author
  • N. E. Korobova
    • 2
  • A. A. Kyrykbaeva
    • 1
  • G. Sh. Yar-Mukhamedova
    • 1
  • K. M. Mukashev
    • 1
  1. Kazakh National UniversityAlmatyKazakhstan
  2. 2.National Research University of Electronic Technology (MIET)MoscowRussia

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