It was found that the spectral and fluorescent properties of BTA-1C cation in protic and aprotic solvents differ. It was shown that for solutions in long-chain alcohols viscosity is the main factor that determines the dynamics of intramolecular charge transfer in the excited state of the BTA-1C molecule. In the case of aprotic solvents a correlation was found between the rate constant of twisted intramolecular charge transfer (TICT) during rotation of fragments of the molecule in relation to each other in the excited state and the solvent relaxation rate: kTICT ~ 1/τ S .
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Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 85, No. 2, pp. 219–225, March–April, 2018.
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Gogoleva, S.D., Stsiapura, V.I. Effect of Viscosity and Polar Properties of Solvent on Dynamics of Photoinduced Charge Transfer in BTA-1 Cation — Derivative of Thioflavin T. J Appl Spectrosc 85, 239–245 (2018). https://doi.org/10.1007/s10812-018-0638-0
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DOI: https://doi.org/10.1007/s10812-018-0638-0