Journal of Applied Spectroscopy

, Volume 85, Issue 1, pp 1–8 | Cite as

Influence of Intermolecular Interactions and Axial Ligands on the Absorption Spectra of Metallophthalocyanines in Solid-State Matrices

  • T. A. Pavich
  • S. M. Arabei
  • K. N. Solovyov

The influences of the structure of the anionic axial ligands in Group-IIIA and -IVA metal–phthalocyanine complexes and intermolecular interactions on the absorption spectra of the macroheterocycles in solutions, an organic polymer, and nanoporous silicate gel matrices were studied. It was shown that anionic Cl – ligands of the central metal ion were effectively substituted for hydroxyls (OH –) during the synthesis and purification of the metallophthalocyanines. Studies of solid-state nanoporous samples obtained by the sol-gel method showed that activator hydroxoaluminumphthalocyanine molecules were incorporated as monomers into the organo-inorganic silicate material. The optically homogeneous luminescent xerogel could be used in optical devices for the wavelength range adjacent to the near-IR region.


metallophthalocyanines sol-gel synthesis nanoporous silicate matrices electronic absorption spectrum IR spectrum ligand exchange monomeric and aggregated forms 


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© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  1. 1.B. I. Stepanov Institute of Physics of the National Academy of Sciences of BelarusMinskBelarus
  2. 2.Belarusian State Agrarian and Technical UniversityMinskBelarus

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