The interaction of the functional groups in the polyurethane foam adsorbent Penopurm® with the cations of some 3d-metals upon their extraction from aqueous solutions has been studied by atomic emission spectroscopy, UV/Vis and vibrational IR spectroscopy, and quantum chemical simulation using density functional theory. Penopurm® absorbs 3d-metal cations from aqueous solutions in the pH range 5–7. Some spectral criteria have been found indicating a predominant interaction of Ni2+ ions with various fragments of the polyurethane foam structure.
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Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 84, No. 5, pp. 758–766, September–October, 2017.
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Ksenofontov, M.A., Bobkova, E.Y., Shundalau, M.B. et al. Quantum Chemical Simulation of the Interaction of Functional Groups in Polyurethanes with 3d-Metal Ions During Their Extraction from Aqueous Solutions. J Appl Spectrosc 84, 816–823 (2017). https://doi.org/10.1007/s10812-017-0550-z
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DOI: https://doi.org/10.1007/s10812-017-0550-z