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Reaction Mechanism of Lead(II) Oxide With A PbCl2–CsCl Melt According to Raman Spectroscopic Data

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Journal of Applied Spectroscopy Aims and scope

The reaction mechanism of lead(II) oxide and PbCl2–CsCl melt was studied in situ using Raman spectroscopy. The types, structures, and compositions of ionic species present in the melt were determined. It was found that dissolution of PbO followed the reaction [PbCl −3  + Cs+](l) + 2 PbO(s) → [Pb3O2Cl+ + Cs+ + 2 Cl] (l) and was accompanied by the appearance of [Pb3O2Cl]+ oxychloride ions.

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Authors and Affiliations

  1. Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences, 22 S. Kovalevskaya Str., Ekaterinburg, 620219, Russia

    I. D. Zakir′yanova & P. A. Arkhipov

  2. B. N. Yeltsin Ural Federal University, Ekaterinburg, Russia

    I. D. Zakir′yanova & D. O. Zakir′yanov

Authors
  1. I. D. Zakir′yanova
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  2. P. A. Arkhipov
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  3. D. O. Zakir′yanov
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Correspondence to I. D. Zakir′yanova.

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Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 82, No. 6, pp. 841–846, November–December, 2015.

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Zakir′yanova, I.D., Arkhipov, P.A. & Zakir′yanov, D.O. Reaction Mechanism of Lead(II) Oxide With A PbCl2–CsCl Melt According to Raman Spectroscopic Data. J Appl Spectrosc 82, 920–924 (2016). https://doi.org/10.1007/s10812-016-0205-5

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  • DOI: https://doi.org/10.1007/s10812-016-0205-5

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