The structure of the low-temperature spectrum of GaP(N) green-light-emitting diodes at 77 and 300 K was due to the recombination of excitons bound to N atoms and NN pairs. All spectral lines were identified. It was concluded that the half-width of the main luminescence line (hν = 2.175 eV, NN1) was due to natural broadening of the initial and final recombination states. It was found that increasing the current through the p–n-junction resulted in the growth of the N-line intensity relative to that of the NN1-line. The intensity redistribution may have been caused by a change of the capture cross-section of minority charge carriers on each center as the injection level increased.
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Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 80, No. 6, pp. 859–863, November– December, 2013.
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Gontaruk, O.N., Kovalenko, A.V., Konoreva, O.V. et al. Electroluminescence of Commercial Gap Green-Light-Emitting Diodes. J Appl Spectrosc 80, 851–854 (2014). https://doi.org/10.1007/s10812-014-9855-3
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DOI: https://doi.org/10.1007/s10812-014-9855-3