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Characteristic features of charge transfer in the interaction between sensitizer molecules and AgCl(I) molecules

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Journal of Applied Spectroscopy Aims and scope

We have used flash luminescence stimulation and photoinduced emission methods to study deep impurity states of AgCl(I) microcrystals with adsorbed organic cationic and anionic dye molecules. We have observed that when these molecules interact with the crystal, charge transfer occurs simultaneously from different orbitals and the transfer occurs differently from each orbital: some orbitals of the molecule pick up a negative charge, others at the same time give up a negative charge. We hypothesize that the type of transfer is determined by the overall charge.

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Authors and Affiliations

  1. Voronezh State University, 1 Universitetskaya pl., Voronezh, Russia

    A. N. Latyshev, Nguyen Thi Kim Chung, T. I. Suvorova, O. V. Ovchinnikov, M. S. Smirnov & E. A. Egorushina

Authors
  1. A. N. Latyshev
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  2. Nguyen Thi Kim Chung
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  3. T. I. Suvorova
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  4. O. V. Ovchinnikov
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  5. M. S. Smirnov
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  6. E. A. Egorushina
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Corresponding author

Correspondence to A. N. Latyshev.

Additional information

Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 78, No. 3, pp. 481–484, May–June, 2011.

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Latyshev, A.N., Chung, N.T.K., Suvorova, T.I. et al. Characteristic features of charge transfer in the interaction between sensitizer molecules and AgCl(I) molecules. J Appl Spectrosc 78, 454–456 (2011). https://doi.org/10.1007/s10812-011-9485-y

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  • DOI: https://doi.org/10.1007/s10812-011-9485-y

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