Results of studies of non-stoichiometric CuInS2 semiconductor by 63Cu and 115In nuclear magnetic resonance are presented. It was established that deviation of the composition from stoichiometry causes a quadrupolebroadened region of the NMR spectrum to change most. In this case a central peak whose shape is governed by the chemical shift anisotropy remains unaffected. NMR spectra reveal two types of structural distortions in the nearest surroundings of the In atoms.
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Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 76, No. 5, pp. 705–709, September–October, 2009.
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Schmidt, E.V., Ermakov, V.L., Gnezdilov, O.I. et al. Structural investigation of non-stoichiometric CuInS2 by 63Cu and 115In nuclear magnetic resonance. J Appl Spectrosc 76, 667–671 (2009). https://doi.org/10.1007/s10812-009-9255-2
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DOI: https://doi.org/10.1007/s10812-009-9255-2