Abstract
The expediency of refining some basic concepts of the common theory of interaction between an electromagnetic field and a substance using a quasi-classical model for the phenomena of absorption and emission of energy and Raman scattering (RS) is considered. The use of the time-dependent Schrodinger equation for obtaining the transition probability constants is discussed. A new model that describes the intensities of the RS lines and involves the explicit introduction of the perturbation operator for the RS spectrum is proposed.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
H. A. Kramers and W. Heisenberg, Z. Phys., 31, 681–708 (1925).
P. A. M. Dirac, Proc. R. Soc. London, A, 114, 710–728 (1927).
V. A. Fok, Introduction to Quantum Mechanics [in Russian], Nauka, Moscow (1976).
J. H. Van Vleck, Proc. Natl. Acad. Sci. USA, 15, 754–764 (1929).
A. C. Albrecht, J. Chem. Phys., 34, 1476–1484 (1961).
J. Tang and A. C. Albrecht, in: Raman Spectroscopy, H. A. Szymanski, ed., Plenum, New York (1970), Vol. 2, 33–68.
F. A. Savin, Opt. Spektrosk., 19, 555–561 (1965).
E. M. Verlan, Opt. Spektrosk., 20, 605–615 (1966).
D. Russo and J. Fridman, in: Raman Spectroscopy in Gases and Liquids, A. Weber, ed., [Russian translation], Mir Moscow (1982).
G. Placzek, in: Handbuch der Radiologie, E. Marx, ed., Academische Verlagsgesellschaft, Leipzig (1934), Vol. 6, 205–274.
M. M. Sushchinskii, Raman Scattering Spectra of Molecules and Crystals [in Russian], Nauka, Moscow (1969).
M. V. Vol’kenshtein, L. A. Gribov, M. A. El’yashevich, and B. I. Stepanov, Molecular Vibrations [in Russian], Nauka, Moscow (1972).
L. A. Gribov, Opt. Spektrosk., 78, 217–220 (1995).
S. V. Trukhanov, L. A. Gribov, and N. I. Prokof’eva, Zh. Strukt. Khim., 37, 241–249 (1996).
S. V. Trukhanov, L. A. Gribov, and N. I. Prokof’eva, Zh. Strukt. Khim., 37, 1006–1015 (1996).
L. A. Gribov, B. K. Novosadov, O. Yu. Nikitin, and L. I. Raitblat, J. Mol. Struct., 188, 175–191 (1989).
Author information
Authors and Affiliations
Corresponding author
Additional information
__________
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 75, No. 3, pp. 309–318, May–June, 2008.
Rights and permissions
About this article
Cite this article
Gribov, L.A. New model describing interaction between an electromagnetic wave and a molecule. J Appl Spectrosc 75, 325–335 (2008). https://doi.org/10.1007/s10812-008-9049-y
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10812-008-9049-y