Abstract
Results of studies on the effect of mechanochemical activation of ligand exchange processes in uranyl perchlorate-dimethylsulfoxide are presented. Spectroscopic data show that mechanical activation of the exchange process in this system results in the replacement of H2O in the first coordination sphere of uranyl UO 2+2 by DMSO to form nanocrystals with a defined ligand sphere. Possible factors governing the noted features are considered.
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Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 75, No. 2, pp. 213–216, March–April, 2008.
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Zazhogin, A.P., Zazhogin, A.A., Komyak, A.I. et al. Composition change of uranium perchlorates with organic ligands upon mechanochemical activation of exchange processes. J Appl Spectrosc 75, 219–222 (2008). https://doi.org/10.1007/s10812-008-9027-4
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DOI: https://doi.org/10.1007/s10812-008-9027-4