Abstract
We have studied quenching of the fluorescence of the diprotonated form of 3,7,13,17-tetramethyl-2,8,12,18-tetrabutylporphyrin by iodide ions in solutions. We have established that there is both static quenching of fluorescence when nonfluorescent complexes are formed with the iodide ions, as a result of an internal heavy atom effect, and also dynamic diffusion-controlled quenching. Based on analysis of the dependences of the fluorescence intensity and fluorescence lifetime on the iodide ion concentration in solution, we suggest using the diprotonated form of this porphyrin as the base compound for designing a fluorescent molecular receptor for halide ions.
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Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 74, No. 6, pp. 750–755, November–December, 2007.
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Kruk, N.N., Starukhin, A.S., Mamardashvili, N.Z. et al. Halide ion determination from luminescence of the diprotonated form of porphyrin. J Appl Spectrosc 74, 831–837 (2007). https://doi.org/10.1007/s10812-007-0129-1
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DOI: https://doi.org/10.1007/s10812-007-0129-1