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Structure of zinc-borate low-melting glasses derived from IR spectroscopy data

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Abstract

The IR spectra of glasses of the ZnO—SrO—B2O3 system with constant additions of PbO, Al2O3, and Li2O (20 mol. % in sum) were studied. It is established that on replacement of B2O3 by ZnO, the structure of the glasses is characterized by the presence of groupings with the bridge bonds BIII— O—BIII, BIII—O—BIV, BIV—O—BIV and end groups BIII— O−; ZnO practically exerts no influence on the coordination transition [BO3] → [BO4]. At a high content of ZnO, zinc ions are present in both a six-and a four-coordinated state.

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Authors and Affiliations

  1. Belarusian State Technological University, 13a Sverdlov Str., Minsk, 220050, Belarus

    N. M. Bobkova & S. A. Khot’ko

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  1. N. M. Bobkova
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  2. S. A. Khot’ko
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Correspondence to N. M. Bobkova.

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Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 72, No. 6, pp. 778–781, November–December, 2005.

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Bobkova, N.M., Khot’ko, S.A. Structure of zinc-borate low-melting glasses derived from IR spectroscopy data. J Appl Spectrosc 72, 853–857 (2005). https://doi.org/10.1007/s10812-006-0015-2

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  • DOI: https://doi.org/10.1007/s10812-006-0015-2

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