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Spectral properties of thin films of modified polycyclohexadiene

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Abstract

Light-sensitive thin films with n-phenylene chains in their structure are formed by deposition from a solution and by thermal vacuum deposition of bromine-modified polycyclohexadiene (Br-PCHD). It is found that the Br-PCHD films possess photoluminescence properties. Using IR-, UV-, and x-ray photoelectron spectroscopy methods, it is shown that during storage and exposure to UV irradiation in air the Br-PCHD films undergo structuring because of having been photooxidized by the molecular oxygen adsorbed on the surface.

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Authors and Affiliations

  1. Institute of Chemistry of New Materials, National Academy of Sciences of Belarus, 36 F. Skorina Str., Minsk, 220141, Belarus

    Zh. D. Chaplanova, Yu. K. Mikhailovskii & V. E. Agabekov

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  1. Zh. D. Chaplanova
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  2. Yu. K. Mikhailovskii
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  3. V. E. Agabekov
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Correspondence to Zh. D. Chaplanova.

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Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 72, No. 6, pp. 722–726, November–December, 2005.

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Chaplanova, Z.D., Mikhailovskii, Y.K. & Agabekov, V.E. Spectral properties of thin films of modified polycyclohexadiene. J Appl Spectrosc 72, 791–795 (2005). https://doi.org/10.1007/s10812-006-0004-5

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  • DOI: https://doi.org/10.1007/s10812-006-0004-5

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