Abstract
We carried out experimental and theoretical investigations of the luminescence characteristics of 1,2,4-triazine derivatives and revealed the factors of a molecular structure that determine the cathodoluminescence wavelength. We obtained a satisfactory agreement between the experimental and calculated spectral characteristics. A number of reasons for the bathochromic and hypsochromic shifts of bands and also a change in the intensity of the pulsed cathodoluminescence were determined. Luminophor fragments of compounds have been revealed. We suggested variants of structural changes to increase the intensity and shift of the luminescence bands.
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REFERENCES
N. N. Mochulskaya, A. A. Andreiko, V. N. Charushin, B. V. Shulgin, D. V. Raikov, and V. I. Solomonov, Mendeleev Commun., 1, 19–21 (2001).
N. N. Mochul'skaya, A. A. Andreiko, L. I. Tarkhov, S. G. Mikhailov, V. I. Solomonov, V. N. Charushin, and B. V. Shulgin, in: Problems of Spectroscopy and Spectrometry [in Russian], Interinstitutional Collection of Sci. Papers of Ural State Technical University-Ural Polytechnical Institute, Vol. 9, Pt. 2 (2002), pp. 71–75.
I. S. Kovalev, L. I. Tarkhov, V. A. Pustovarov, V. L. Rusinov, and B. V. Shulgin, in: Proc. III Ural Workshop on Advantaged Scintillation and Storage Optical Material, Russia, Ekaterinburg (2002), pp. 54–58.
L. I. Tarkhov, D. N. Kozhevnikov, and B. V. Shulgin, in: Proc. 12th Int. Conf. on Radiation Physics and Chemistry of Inorganic Materials, Tomsk (2003), pp. 560–563.
B. V. Shulgin, L. I. Tarkhov, D. N. Kozhevnikov, M. M. Ustinova, and V. I. Solomonov, in: Proc. 7th Int. Conf. on Inorganic Scintillators and Industrial Application, Valencia, Spain (2003), p. 99.
L. I. Tarkhov, D. N. Kozhevnikov, I. S. Kovalev, B. V. Shulgin, and A. A. Shalaev, in: Proc. 2nd Integration Interdisciplinary Conf. of Young Scientists of the Siberian Branch of the Russian Academy of Sciences and Higher School [in Russian], Irkutsk (2003), pp. 159–165.
V. I. Solomonov and S. G. Mikhailov, Pulse Cathodoluminescence and Its Application to Analysis of Condensed Matter [in Russian], Izd. UrO RAN, Ekaterinburg (2003).
V. A. Potemkin, E. V. Bartashevich, M. A. Grishina, and S. Guccione, in: Proc. 13th Eur. Symp. on Quantitative Structure-Activity Relationships, QSAR 2000, Dusseldorf, Germany (2000), pp. 349–353.
M. A. Grishina, V. A. Potemkin, G. L. Rusinov, E. V. Bartashevich, S. Guccione, S. Perspicace, and O. N. Chupakhin, in: From Genes to Drugs via Crystallography, 33rd Crystallographic Course, Erice, Italy (2002), p. 48.
V. A. Potemkin, E. V. Bartashevich, A. R. Beccari, M. A. Grishina, and S. Guccione, in: Proc. 13th Eur. Symp. on Quantitative Structure-Activity Relationships, QSAR 2000, Dusseldorf, Germany (2000), p. 110.
K. Mikuchina, V. A. Potemkin, M. A. Grishina, and S. Laufer, Arch. Pharm. Pharm. Med. Chem., 1, 74 (2002).
V. A. Potemkin, M. A. Grishina, A. V. Belik, and O. N. Chupakhin, Khim.-Farm. Zh., 1, 22–25 (2002).
O. V. Fedorova, G. L. Rusinov, M. A. Grishina, V. A. Potemkin, I. G. Ovchinnikova, V. A. Popova, M. S. Zhidovinova, and O. N. Chupakhin, in: V. I. Saloutin and O. V. Fedorova (Eds.), Urgent Problems of the Chemistry and Technology of Organic Substances. History, Problems of Organic Synthesis, Perspectives [in Russian], Izd. UrO RAN, Ekaterinburg (2002), pp. 321–340.
M. A. Grishina and V. A. Potemkin, in: Proc. IX Int. Seminar on Inclusion Compounds (ISIC-9), Novosibirsk (2003), p 73.
V. A. Potemkin, M. A. Grishina, O. V. Fedorova, G. L. Rusinov, I. G. Ovchinnikova, and R. I. Ishmetova, Khim.-Farm. Zh., 9, 24–28 (2003).
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Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 72, No. 5, pp. 586–590, September–October, 2005.
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Tarkhov, L.I., Potemkin, V.A. & Kozhevnikov, D.N. Experimental Investigation and Modeling of the Cathodoluminescence of 1,2,4-Triazine Derivatives. J Appl Spectrosc 72, 636–642 (2005). https://doi.org/10.1007/s10812-005-0126-1
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DOI: https://doi.org/10.1007/s10812-005-0126-1