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Use of Capillary Gas Chromatography for Determining Hydrocarbons in High-Purity Silane

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Abstract

A procedure was proposed for the 2D gas-chromatographic determination of C1-C4 hydrocarbons in high-purity silane. The impurities were separated in a capillary column with a newly proposed adsorbent, poly(trimethylsilylpropyne). The detection limits for the impurities are (2−6) × 10−7 vol %, which is 2.5–15 times lower than those found in the literature.

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Authors and Affiliations

  1. Department of Chemistry, Nizhni Novgorod State University, pr, Gagarina 23, Nizhni Novgorod, 603600, Russia

    V. A. Krylov

  2. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninskii pr. 29, Moscow, 119991, Russia

    V. G. Berezkin & A. Yu. Sozin

  3. Institute of High-Purity Substances, Russian Academy of Sciences, ul. Tropinina 49, Nizhni Novgorod, 603600, Russia

    O. Yu. Chernova & Yu. M. Salganskii

Authors
  1. V. A. Krylov
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  2. V. G. Berezkin
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  3. O. Yu. Chernova
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  4. Yu. M. Salganskii
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  5. A. Yu. Sozin
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__________

Translated from Zhurnal Analiticheskoi Khimii, Vol. 60, No. 9, 2005, pp. 958–962.

Original Russian Text Copyright © 2005 by Krylov, Berezkin, Chernova, Salganskii, Sozin.

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Krylov, V.A., Berezkin, V.G., Chernova, O.Y. et al. Use of Capillary Gas Chromatography for Determining Hydrocarbons in High-Purity Silane. J Anal Chem 60, 851–854 (2005). https://doi.org/10.1007/s10809-005-0194-7

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  • DOI: https://doi.org/10.1007/s10809-005-0194-7

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