Skip to main content
SpringerLink
Log in

Electrophoretic and spectrophotometric determination of iodohalides of P-containing organic cations

  • Articles
  • Published:
Journal of Analytical Chemistry Aims and scope Submit manuscript

Abstract

Diiodobromides of P-containing organic cations, 3-carboxypropyltriphenylphosphonium (I) and tetraphenylphosphonium(II), were identified and quantitatively determined by capillary electrophoresis using an unmodified fused-silica capillary. The procedure for the quantitative determination of I and II by capillary electrophoresis allowed the organophosphorus compounds to be determined in the concentration range from 0.20 to 6.0 mM (RSD≤1%). The spectrophotometric method based on the conversion of diiodobromides to the corresponding triiodides (ε290 = 4.6 × 104,ε367 = 2.5 × 104) and followed by the measurement of the intensity of the band of the triiodide ion charge-transfer (RSD≤2%) was proposed to determine iodohalides of P-containing cations.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. Rideout, D.C., Calogeropoulou, T., Jaworski, J.S., et al., Anti-Cancer Drug Design, 1989, vol. 4, no. 2, p. 65.

    Google Scholar 

  2. Kaimachnikov, N.P., Abstracts of Papers, 16th FEBS Meeting, Moscow, 1984, p. 439.

  3. Abraham, W., J. Inclus. Phenom. Macro., 2002, vol. 43, p. 159.

    Google Scholar 

  4. Ba-Isa, A., Busch, K.L., and Cooks, R.G., Tetrahedron, 1983, vol. 39, no. 4, p. 591.

    Google Scholar 

  5. Kazheva, O.N., Aleksandrov, G.G., D’yachenko, O.A., et al., Koord. Khim., 2003, vol. 29, no. 12, p. 883 [Russ. J. Inorg. Chem. (Engl. Transl.), vol. 29, no. 12, p. 819].

    Google Scholar 

  6. Kazheva, O.N., Aleksandrov, G.G., D’yachenko, O.A., et al., Koord. Khim., 2004, vol. 30, no. 7 [Russ. J. Inorg. Chem. (Engl. Transl.), vol. 30, no. 7].

  7. Mosulishvili, L.M., Barnov, V.A., Tsibakhashvilli, N.Ya., et al., Zh. Anal. Khim., 2001, vol. 56, no. 6, p. 579 [J. Anal. Chem. (Engl. Transl.), 2001, vol. 56, no. 6, p. 512].

    Google Scholar 

  8. Krokhin, O.V., Pirogov, A.V., and Shpigun, O.A., Zh. Anal. Khim., 2002, vol. 57, no. 10, p. 1087 [J. Anal. Chem. (Engl. Transl.), 2002, vol. 57, no. 10, p. 920].

    Google Scholar 

  9. Kuijt, J., Teylingen, R., Nijbacker, T.N., et al., Anal. Chem., 2001, vol. 73, p. 5026.

    Google Scholar 

  10. Duso, A.B. and Chen David, D.Y., Anal. Chem., 2002, vol. 74, no. 29, p. 2938.

    Google Scholar 

  11. Chernov’yants, M.S., Gol’eva, V.E., and Pyshchev, A.I., Zh. Anal. Khim., 2003, vol. 58, no. 2, p. 161 [J. Anal. Chem. (Engl. Transl.), 2003, vol. 58, no. 2, p. 139].

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Rostov State University, ul. Zorge 7, 344090, Rostov-on-Don, Russia

    M. S. Chernov’yants & E. O. Lykova

Authors
  1. M. S. Chernov’yants
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. O. Lykova
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Zhurnal Analiticheskoi Khimii, Vol. 60, No. 2, 2005, pp. 162–164.

Original Russian Text Copyright © 2005 by Chernov’yants, Lykova.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Chernov’yants, M.S., Lykova, E.O. Electrophoretic and spectrophotometric determination of iodohalides of P-containing organic cations. J Anal Chem 60, 141–143 (2005). https://doi.org/10.1007/s10809-005-0042-9

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10809-005-0042-9

Keywords

Search

Navigation