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Fluorimetric determination of tetracyclines with the europium chelate of 1,10-phenanthroline in micellar solutions of anionic surfactants

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Abstract

The fluorescence of europium(III) in micellar solutions of surfactants sensitized by tetracycline derivatives was studied. It was found that the fluorescence intensity in the system Eu 3+ -tetracycline derivatives increases in the presence of 1,10-phenanthroline by a factor of 3–4. In micellar solutions of sodium dodecylbenzene sulfonate, the signal additionally enhances by a factor of 2.5. A procedure was developed for determining tetracycline and three its derivatives in blood plasma.

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Translated from Zhurnal Analiticheskoi Khimii, Vol. 60, No. 1, 2005, pp. 30–34.

Original Russian Text Copyright © 2005 by Shtykov, Smirnova, Bylinkin, Zhemerichkin.

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Shtykov, S.N., Smirnova, T.D., Bylinkin, Y.G. et al. Fluorimetric determination of tetracyclines with the europium chelate of 1,10-phenanthroline in micellar solutions of anionic surfactants. J Anal Chem 60, 24–28 (2005). https://doi.org/10.1007/s10809-005-0007-z

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  • DOI: https://doi.org/10.1007/s10809-005-0007-z

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