Skip to main content
Log in

Using Rotational Raman Scattering to Study Gas Impurities

  • Published:
Journal of Applied Mechanics and Technical Physics Aims and scope

Abstract

The use of optical diagnostic methods (spontaneous Raman scattering and coherent anti-Stokes light scattering) to measure gas impurity concentrations of less than 0. 1% is studied. The shapes of measured and calculated rotational Raman scattering spectra were compared to process experimental data. The technique was tested for measuring nitrogen, oxygen, and hydrogen concentrations in jets. Under the conditions of these experiments, changes in the ratio of oxygen and nitrogen concentrations during air diffusion into helium and hydrogen were not observed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. B. V. Lukashov and S. V. Zhilivostova, “On the manifestation of multicomponent diffusion in a laminar boundary layer with impurity injection,” Teplofiz. A’eromekh., 15, No. 3, 505–511 (2008).

    Google Scholar 

  2. M. S. Makarov, “Numerical method for multicomponent diffusion with a posteriori evaluation of calculation accuracy on the basis of mass balance,” Int. J. Heat Mass Transfer, 52, Nos. 7/8, 1769–1773 (2009).

    Article  MATH  Google Scholar 

  3. O. P. Korobeinichev, A. G. Tereshchenko, I. D. Emel’yanov, et al., “Substantiation of the probe mass-spectrometric method for studying the structure of flames with narrow combustion zones,” Combust., Expl., Shock Waves, 21, No. 5, 524–530 (1985).

    Article  Google Scholar 

  4. J. C. Luthe, E. J. Beiting, and F. Y. Yueh, “Algorithms for calculating coherent anti-Stokes Raman spectra: Application to several small molecules,” Comput. Phys. Comm., 42, 73–92 (1986).

    Article  ADS  Google Scholar 

  5. K. P. Huber and G. Herzberg, Molecular Spectra and Molecular Structure, Vol. 4: Constants of Diatomic Molecules, Reinhold, New York (1979).

    Google Scholar 

  6. A. Weber, “High resolution rotational Raman spectra of gases,” in: A. Weber (ed.), Raman Spectroscopy in Gases and Liquids, Springer-Verlag, New York-Belrin (1979).

    Google Scholar 

  7. H. Schretter and H. Klekner, “Raman scattering cross sections in gases and liquids,” in: A. Weber (ed.), Raman Spectroscopy in Gases and Liquids, Springer-Verlag, New York-Belrin (1979).

    Google Scholar 

  8. C. M. Penney, R. L. St. Peters, and M. Lapp, “Absolute rotational Raman cross sections for N2, O2, and CO2,” J. Opt. Soc. Amer., 64, No. 5, 712–716 (1974).

    Article  ADS  Google Scholar 

  9. K. S. Jammu, G. E. St. John, and H. L. Welsh, “Pressure broadening of the rotational Raman lines of some simple gases,” Canad. J. Phys., 44, 797–814 (1966).

    ADS  Google Scholar 

  10. B. F. Boyarshinov and S. Y. Fedorov, “Measuring parameters of rotational gas flow by the coherent anti-Stokes light scattering method,” Prib. Tekh. Éksp., No. 6, 95–99 (1999).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to S. Yu. Fedorov.

Additional information

Translated from Prikladnaya Mekhanika i Tekhnicheskaya Fizika, Vol. 51, No. 5, pp. 177–186, September–October, 2010

Rights and permissions

Reprints and permissions

About this article

Cite this article

Boyarshinov, B.F., Fedorov, S.Y. Using Rotational Raman Scattering to Study Gas Impurities. J Appl Mech Tech Phy 51, 769–775 (2010). https://doi.org/10.1007/s10808-010-0097-8

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10808-010-0097-8

Key words

Navigation