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Equilibrium self-polarization of clay

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Journal of Applied Mechanics and Technical Physics Aims and scope

Abstract

A condition of equilibrium between charged clay particle surfaces and the solution contained in the pore space of the rock is derived using electrical double layer theory. This condition is the relation linking the cation concentration in the middle surface of the pores with the exchange capacity of the clay, the total ion charges, and the specific surface area of the particles.

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References

  1. D. A. Shapiro, “Some questions of the theory of diffusion-adsorption (membrane) potentials in boreholes,” Applied Geophysics (collected scientific papers) [in Russian], No. 19, Gostoptekhizdat, Moscow (1958), pp. 129–169.

    Google Scholar 

  2. V. N. Dakhnov and L. P. Dolina, Geophysical Methods of Studying Oil and Gas Bearing Collectors [in Russian], Gostoptekhizdat, Moscow (1959).

    Google Scholar 

  3. G. Gony, “Sur la constitution de la charge electrique a la surface d’un electrolute,” Ann. Phys. (Paris), Ser. 4, 457–468 (1910).

    Google Scholar 

  4. D. L. Chapman, “A contribution to the theory of electrocapillarity,” Philos. Mag., 25, 475–481 (1913).

    Google Scholar 

  5. O. Stern, “Zur Theorie der electrolytischen Doppelschicht,” Z. Electrochem., 30, 508–516 (1924).

    Google Scholar 

  6. F. A. M. Haan, “The negative adsorption of anions (anion exclusion) in systems with interacting double layers,” J. Phys. Chem., 68, No. 10, 2970–2977 (1964).

    Article  Google Scholar 

  7. W. D. Kemper, I. Sheinberg, and J. P. Quirk, “Swelling pressure, electric potentials and ion concentration: their role in hydraulic and osmotic flow through clays,” Soil Sci. Amer. Proc., 36, No. 2, 229–236 (1972).

    Article  Google Scholar 

  8. I. Ravina and Y. Gur, “Application of the electrical double layer theory to predict ion adsorption in mixed ionic systems,” Soil Sci., 125, No. 4, 204–209 (1978).

    Article  Google Scholar 

  9. S. A. Guzeev and V. V. Kormil’tsev, “Determination of the adsorption potential via double-layer characteristics,” Ural. Geofiz. Vest., 6, 22–28 (2004).

    Google Scholar 

  10. P. Ya. Polubarinova-Kochina, Theory of Motion of Soil Water [in Russian], Nauka, Moscow (1977).

    Google Scholar 

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Translated from Prikladnaya Mekhanika i Tekhnicheskaya Fizika, Vol. 48, No. 5, pp. 96–103, September–October, 2007.

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Korsakova, N.K., Pen’kovskii, V.I. Equilibrium self-polarization of clay. J Appl Mech Tech Phys 48, 701–707 (2007). https://doi.org/10.1007/s10808-007-0090-z

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  • DOI: https://doi.org/10.1007/s10808-007-0090-z

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