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Journal of Applied Electrochemistry

, Volume 48, Issue 7, pp 811–817 | Cite as

Carbon/tin oxide composite electrodes for improved lithium-ion batteries

  • Yunchao Li
  • Alan M. Levine
  • Jinshui Zhang
  • Richard J. Lee
  • Amit K. Naskar
  • Sheng Dai
  • M. Parans Paranthaman
Research Article
  • 221 Downloads
Part of the following topical collections:
  1. Batteries

Abstract

Tin and tin oxide-based electrodes are promising high-capacity anodes for lithium-ion batteries. However, poor capacity retention is the major issue with these materials due to the large volumetric expansion that occurs when lithium is alloyed with tin during lithiation and delithiation process. Here, a method to prepare a low-cost, scalable carbon and tin(II) oxide composite anode is reported. The composite material was prepared by ball milling of carbon recovered from used tire powders with 25 wt% tin(II) oxide to form lithium-ion battery anode. With the impact of energy from the ball milling, tin oxide powders were uniformly distributed inside the pores of waste-tire-derived carbon. During lithiation and delithiation, the carbon matrix can effectively absorb the volume expansion caused by tin, thereby minimizing pulverization and capacity fade of the electrodes. The as-synthesized anode yielded a capacity of 690 mAh g−1 after 300 cycles at a current density of 40 mA g−1 with a stable battery performance.

Graphical abstract

A method to prepare low-cost carbon/tin (II) oxide (SnO) composite by ball milling is reported. SnO powders are uniformly distributed inside the carbon matrix, which could effectively absorb the volume expansion of Sn and alleviate capacity fade. The anode yields a capacity of 690 mAh g−1 after 300 cycles.

Keywords

Lithium-ion batteries (LIBs) Composite carbon anodes Tin oxide Waste tire recycling Ball milling 

Notes

Acknowledgements

This research was sponsored by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, Materials Sciences and Engineering Division.

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Copyright information

© This is a U.S. Government work and not under copyright protection in the US; foreign copyright protection may apply 2018

Authors and Affiliations

  • Yunchao Li
    • 1
    • 2
  • Alan M. Levine
    • 4
  • Jinshui Zhang
    • 1
  • Richard J. Lee
    • 4
  • Amit K. Naskar
    • 2
    • 3
  • Sheng Dai
    • 1
  • M. Parans Paranthaman
    • 1
    • 2
  1. 1.Chemical Sciences DivisionOak Ridge National LaboratoryOak RidgeUSA
  2. 2.The Bredesen Center for Interdisciplinary Research and Graduate EducationThe University of TennesseeKnoxvilleUSA
  3. 3.Materials Science and Technology DivisionOak Ridge National LaboratoryOak RidgeUSA
  4. 4.RJ Lee GroupMonroevilleUSA

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