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Journal of Applied Electrochemistry

, Volume 47, Issue 7, pp 777–788 | Cite as

Improved dye entrapment–liberation performance at electrochemically synthesised polypyrrole–reduced graphene oxide nanocomposite films

  • Md Mominul Haque
  • Danny K. Y. Wong
Research Article
  • 181 Downloads
Part of the following topical collections:
  1. Remediation

Abstract

In this work, we have reported the application of electropolymerised polypyrrole–reduced graphene oxide (Ppy–RGO) nanocomposite films as an effective tool for entrapping and liberating the model dye Acid Red 1, and thereby proposed this as an ecofriendly treatment for dye-containing textile effluents. Initially, a polypyrrole–graphene oxide (Ppy–GO) nanocomposite film was anodically synthesised by an in situ electropolymerisation of pyrrole and GO. The Ppy–GO film was then electrochemically reduced to form a Ppy–RGO nanocomposite film. The synthesised nanocomposite films were characterised by spectroscopy, microscopy, surface analysis and thermogravimetry. Brunauer, Emmett and Teller surface area analysis showed a 7.4-fold increase in surface area of Ppy–RGO films compared to that of \({\text{NO}}_{3}^{ - }\)-polypyrrole films. In addition, based on tensile strength, Ppy–RGO films were demonstrated to be 12.7-folds mechanically stronger than \({\text{NO}}_{3}^{ - }\)–Ppy films. When Acid Red 1 was entrapped in these films, an entrapment efficiency of as high as 95% for Acid Red 1 was achieved at Ppy–RGO films, which is significantly higher than 56% achieved at Ppy films. Similarly, while liberating the entrapped Acid Red 1 from the Ppy–RGO nanocomposite films, a liberation efficiency of 73% was estimated compared to 36% from the Ppy films.

Graphical abstract

Keywords

Polypyrrole–reduced graphene oxide Acid Red 1 Dye entrapment Dye liberation Textile effluents, nanocomposite films 

Notes

Acknowledgements

The funding was provided by Macquarie University.

References

  1. 1.
    Ayad MM, El-Nasr AA (2010) Adsorption of cationic dye (methylene blue) from water using polyaniline nanotubes base. J Phys Chem C 114:14377–14383CrossRefGoogle Scholar
  2. 2.
    Carmen Z, Daniela S (2012) Textile organic dyes-characteristics, polluting effects and separation/elimination procedures from industrial effluents–a critical overview. In: Puzyn DT (ed) Organic pollutants ten years after the Stockholm Convention-Environmental and Analytical Update. Intech, Croatia, pp 55–86Google Scholar
  3. 3.
    Gong R, Sun Y, Chen J, Liu H, Yang C (2005) Effect of chemical modification on dye adsorption capacity of peanut hull. Dyes Pigm 67:175–181CrossRefGoogle Scholar
  4. 4.
    Hameed BH (2009) Removal of cationic dye from aqueous solution using jackfruit peel as non-conventional low-cost adsorbent. J Hazard Mater 162:344–350CrossRefGoogle Scholar
  5. 5.
    Haque MM, Smith WT, Wong DKY (2015) Conducting polypyrrole films as a potential tool for electrochemical treatment of azo dyes in textile wastewaters. J Hazard Mater 283:164–170CrossRefGoogle Scholar
  6. 6.
    Haque MM, Wong DKY (2015) Kinetic model and thermodynamic studies of Acid Red 1 entrapment at electropolymerised polypyrrole films. J Colloid Interface Sci 457:188–194CrossRefGoogle Scholar
  7. 7.
    Konwer S, Boruah R, Dolui S (2011) Studies on conducting polypyrrole/graphene oxide composites as supercapacitor electrode. J Electron Mater 40:2248–2255CrossRefGoogle Scholar
  8. 8.
    Frackowiak E, Khomenko V, Jurewicz K, Lota K, Beguin F (2006) Supercapacitors based on conducting polymers/nanotubes composites. J Power Sources 153:413–418CrossRefGoogle Scholar
  9. 9.
    Zhang L, Shi G (2011) Preparation of highly conductive graphene hydrogels for fabricating supercapacitors with high rate capability. J Phys Chem C 115:17206–17212CrossRefGoogle Scholar
  10. 10.
    Bora C, Dolui S (2012) Fabrication of polypyrrole/graphene oxide nanocomposites by liquid/liquid interfacial polymerization and evaluation of their optical, electrical and electrochemical properties. Polymer 53:923–932CrossRefGoogle Scholar
  11. 11.
    Hummers WS Jr, Offeman RE (1958) Preparation of graphitic oxide. J Am Chem Soc 80:1339CrossRefGoogle Scholar
  12. 12.
    Brunauer S, Emmett PH, Teller E (1938) Adsorption of gases in multimolecular layers. J Am Chem Soc 60:309–319CrossRefGoogle Scholar
  13. 13.
    Krishnakumar B, Swaminathan M (2011) Influence of operational parameters on photocatalytic degradation of a genotoxic azo dye Acid Violet 7 in aqueous ZnO suspensions. Spectrochim Acta Mol Biomol Spectrosc 81:739–744CrossRefGoogle Scholar
  14. 14.
    Witkowski A, Freund MS, Brajter-Toth A (1991) Effect of electrode substrate on the morphology and selectivity of overoxidized polypyrrole films. Anal Chem 63:622–626CrossRefGoogle Scholar
  15. 15.
    Schlenoff JB, Xu H (1992) Evolution of physical and electrochemical properties of polypyrrole during extended oxidation. J Electrochem Soc 139:2397–2401CrossRefGoogle Scholar
  16. 16.
    Beck F, Braun P, Oberst M (1987) Organic electrochemistry in the solid state-overoxidation of polypyrrole. Ber Bunsen Phys Chem 91:967–974CrossRefGoogle Scholar
  17. 17.
    Feng X, Li R, Yan Z, Liu X, Chen R, Ma Y, Xa Li, Fan Q, Huang W (2012) Preparation of graphene/polypyrrole composite film via electrodeposition for supercapacitors. IEEE Trans Nanotechnol 11:1080–1086CrossRefGoogle Scholar
  18. 18.
    Zhang D, Luo L, Liao Q, Wang H, Fu H, Yao J (2011) Polypyrrole/ZnS core/shell coaxial nanowires prepared by anodic aluminum oxide template methods. J Phys Chem C 115:2360–2365CrossRefGoogle Scholar
  19. 19.
    Si P, Ding S, Lou X-W, Kim D-H (2011) An electrochemically formed three-dimensional structure of polypyrrole/graphene nanoplatelets for high-performance supercapacitors. RSC Adv 1:1271–1278CrossRefGoogle Scholar
  20. 20.
    Chang H-H, Chang C-K, Tsai Y-C, Liao C-S (2012) Electrochemically synthesized graphene/polypyrrole composites and their use in supercapacitor. Carbon 50:2331–2336CrossRefGoogle Scholar
  21. 21.
    Liu AS, Bezerra MC, Cho LY (2009) Electrodeposition of polypyrrole films on aluminum surfaces from a p-toluene sulfonic acid medium. Mater Res 12:503–507CrossRefGoogle Scholar
  22. 22.
    Yang Y, Wang C, Yue B, Gambhir S, Too CO, Wallace GG (2012) Electrochemically synthesized polypyrrole/graphene composite film for lithium batteries. Adv Energy Mater 2:266–272CrossRefGoogle Scholar
  23. 23.
    Chandra V, Kim KS (2011) Highly selective adsorption of Hg2+ by a polypyrrole-reduced graphene oxide composite. Chem Commun 47:3942–3944CrossRefGoogle Scholar
  24. 24.
    Lim Y, Tan YP, Lim HN, Tan WT, Mahnaz M, Talib ZA, Huang NM, Kassim A, Yarmo MA (2013) Polypyrrole/graphene composite films synthesized via potentiostatic deposition. J Appl Polym Sci 128:224–229CrossRefGoogle Scholar
  25. 25.
    Liu A, Li C, Bai H, Shi G (2010) Electrochemical deposition of polypyrrole/sulfonated graphene composite films. J Phys Chem C 114:22783–22789CrossRefGoogle Scholar
  26. 26.
    Bose S, Kim NH, Kuila T, Lau K-T, Lee JH (2011) Electrochemical performance of a graphene–polypyrrole nanocomposite as a supercapacitor electrode. Nanotechnology 22:295202CrossRefGoogle Scholar
  27. 27.
    Liu J, Wang Z, Xie X, Cheng H, Zhao Y, Qu L (2012) A rationally-designed synergetic polypyrrole/graphene bilayer actuator. J Mater Chem 22:4015–4020CrossRefGoogle Scholar
  28. 28.
    Kuilla T, Bhadra S, Yao D, Kim NH, Bose S, Lee JH (2010) Recent advances in graphene based polymer composites. Prog Polym Sci 35:1350–1375CrossRefGoogle Scholar
  29. 29.
    Bissessur R, Liu PKY, Scully SF (2006) Intercalation of polypyrrole into graphite oxide. Synth Met 156:1023–1027CrossRefGoogle Scholar
  30. 30.
    Li J, Feng J, Yan W (2013) Excellent adsorption and desorption characteristics of polypyrrole/TiO2 composite for Methylene Blue. Appl Surf Sci 279:400–408CrossRefGoogle Scholar
  31. 31.
    Li J, Feng J, Yan W (2013) Synthesis of polypyrrole-modified TiO2 composite adsorbent and its adsorption performance on acid Red G. J Appl Polym Sci 128:3231–3239CrossRefGoogle Scholar
  32. 32.
    Pickup NL, Shapiro JS, Wong DK (2001) Extraction of mercury and silver into base-acid treated polypyrrole films: a possible pollution control technology. J Polym Res 8:151–157CrossRefGoogle Scholar
  33. 33.
    Forsyth M, Truong V-T (1995) A study of acid/base treatments of polypyrrole films using 13 C nmr spectroscopy. Polymer 36:725–730CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media Dordrecht 2017

Authors and Affiliations

  1. 1.Department of Chemistry and Biomolecular SciencesMacquarie UniversitySydneyAustralia

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