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Journal of Applied Electrochemistry

, Volume 46, Issue 2, pp 149–155 | Cite as

Ionic liquid-based electrolytes for lithium-ion batteries: review of performances of various electrode systems

  • Hassan Srour
  • Léa Chancelier
  • Ewelina Bolimowska
  • Thibaut Gutel
  • Sophie Mailley
  • Hélène Rouault
  • Catherine C. SantiniEmail author
Research Article
Part of the following topical collections:
  1. Batteries

Abstract

Lithium-ion cells based on Graphite/LiFePO4 (Cgr/LFP), Li4Ti5O12/LiFePO4 (LTO/LFP) and Li4Ti5O12/LiNi1/3Mn1/3Co1/3O2 (LTO/NMC), using [C1C n Im][NTf2]- and [C1C1C n Im][NTf2] (n = 4 and 6)-based electrolytes with different lithium salts such as Li[N(SO2CF3)2] (LiNTf2), Li[N(SO2F)2] (LiFSI) and LiPF6 were tested at 333 K and compared to a commercial carbonate-based electrolyte [EC:DEC][LiPF6]. The impact of different factors such as length of side-alkyl chain on imidazolium ring or its C2-H substitution with CH3 group was studied, and the influence of the presence of organic additives as well as the value of the nominal voltage of the systems, was also reported. Finally, common trends for all these IL-based electrolyte systems were discussed.

Keywords

Li-ion battery Ionic liquid-based electrolytes Cycling performance 

Notes

Acknowledgments

The authors wish to thank Dr. Karim Zaghib (Institut de recherche d’Hydro-Québec) for LiFSI sample, and Djamel Mourzagh for his technical support.

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Copyright information

© Springer Science+Business Media Dordrecht 2015

Authors and Affiliations

  • Hassan Srour
    • 1
    • 2
  • Léa Chancelier
    • 1
    • 2
  • Ewelina Bolimowska
    • 1
    • 2
  • Thibaut Gutel
    • 2
  • Sophie Mailley
    • 2
  • Hélène Rouault
    • 2
  • Catherine C. Santini
    • 1
    Email author
  1. 1.UMR 5265 CNRS-C2P2VilleurbanneFrance
  2. 2.CEA, LITENGrenoble Cedex 9France

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