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Journal of Applied Electrochemistry

, Volume 45, Issue 9, pp 983–990 | Cite as

Characteristics of Fe2O3/exfoliated vapor-grown carbon fiber composite as anode material for lithium-ion batteries

  • Jae-Hun Jeong
  • Eun-Suok OhEmail author
Research Article
Part of the following topical collections:
  1. Batteries

Abstract

The effect of exfoliation of vapor-grown carbon fiber (VGCF) on the electrochemical properties as an anode of lithium-ion batteries was thoroughly investigated by diverse characterization tools. The exfoliation by the ball milling followed by the acid and heat treatments changed several morphological features such as decreased length, wider interlayer spacing, and even exfoliation of the layer. Moreover, numerous defects including functional groups were observed when the VGCF was exfoliated, increasing the deposition of Fe2O3 on its surface. Owing to these advantages, the exfoliated-VGCF exhibited significantly enhanced C-rate capability with high reversible capacity even though its initial irreversible capacity increased compared to the pristine VGCF. In particular, the Fe2O3/exfoliated-VGCF composite anodes have a good cycle stability with a high capacity of 936 mA h g−1 after 50th discharge at a C-rate of 100 mA g−1.

Keywords

Vapor-grown carbon fiber Graphene Fe2O3 Exfoliation Anode material Lithium-ion battery 

Notes

Acknowledgments

The work was supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education (2014R1A1A2055793).

Conflict of interest

The authors declare that they have no conflict of interest.

References

  1. 1.
    Liang M, Zhi L (2009) Graphene-based electrode materials for rechargeable lithium batteries. J Mater Chem 19:5871–5878CrossRefGoogle Scholar
  2. 2.
    Kim K-S, Park S-J (2011) Synthesis of carbon-coated graphene electrodes and their electrochemical performance. Electrochim Acta 56:6547–6553CrossRefGoogle Scholar
  3. 3.
    Fan Z-J, Yan J, Wei T, Ning G-Q, Zhi L-J, Liu J-C, Cao D-X, Wang G-L, Wei F (2011) Nanographene-constructed carbon nanofibers grown on graphene sheets by chemical vapor deposition: high-performance anode materials for lithium ion batteries. ACS Nano 5:2787–2794CrossRefGoogle Scholar
  4. 4.
    Wang C, Li D, Too CO, Wallace GG (2009) Electrochemical properties of graphene paper electrodes used in lithium batteries. Chem Mater 21:2604–2606CrossRefGoogle Scholar
  5. 5.
    Pham-Cong D, Ahn K, Hong SW, Jeong SY, Choi JH, Doh CH, Jin JS, Jeong ED, Cho CR, Rousset A (2014) Cathodic performance of V2O5 nanowires and reduced graphene oxide composites for lithium ion batteries. Curr Appl Phys 14:215–221CrossRefGoogle Scholar
  6. 6.
    Abouimrane A, Compton OC, Amine K, Nguyen ST (2010) Non-annealed graphene paper as a binder-free anode for lithium-ion batteries. J Phys Chem C 114:12800–12804CrossRefGoogle Scholar
  7. 7.
    Brownson DAC, Kampouris DK, Banks CE (2011) An overview of graphene in energy production and storage applications. J Power Sources 196:4873–4885CrossRefGoogle Scholar
  8. 8.
    Lee JK, Smith KB, Hayner CM, Kung HH (2010) Silicon nanoparticles-graphene paper composites for Li ion battery anodes. Chem Commun 46:2025–2027CrossRefGoogle Scholar
  9. 9.
    Zhao X, Hayner CM, Kung MC, Kung HH (2011) In-plane vacancy-enabled high-power Si–graphene composite electrode for lithium-ion batteries. Adv Energy Mater 1:1079–1084CrossRefGoogle Scholar
  10. 10.
    Mizuno F, Hayashi A, Tadanaga K, Tatsumisago M (2005) Effects of conductive additives in composite positive electrodes on charge-discharge behaviors of all-solid-state lithium secondary batteries. J Electrochem Soc 152:A1499–A1503CrossRefGoogle Scholar
  11. 11.
    Wu MS, Lee JT, Chiang PC, Lin JC (2007) Carbon-nanofiber composite electrodes for thin and flexible lithium-ion batteries. J Mater Sci 42:259–265CrossRefGoogle Scholar
  12. 12.
    Park JK (2010) Principles and applications of lithium secondary batteries, 1st edn. Hongrung, SeoulGoogle Scholar
  13. 13.
    Endo M, Kim YA, Hayashi T, Nishimura K, Matusita T, Miyashita K, Dresselhaus MS (2001) Vapor-grown carbon fibers (VGCFs): basic properties and their battery applications. Carbon 39:1287–1297CrossRefGoogle Scholar
  14. 14.
    Abe H, Murai T, Zaghib K (1999) Vapor-grown carbon fiber anode for cylindrical lithium ion rechargeable batteries. J Power Sources 77:110–115CrossRefGoogle Scholar
  15. 15.
    Zaghib K, Tatsumi K, Abe H, Ohsaki T, Sawada Y, Higuchi S (1998) Optimization of the dimensions of vapor-grown carbon fiber for use as negative electrodes in lithium-ion rechargeable cells. J Electrochem Soc 145:210–215CrossRefGoogle Scholar
  16. 16.
    Subramanian V, Zhu H, Wei B (2006) High rate reversibility anode materials of lithium batteries from vapor-grown carbon nanofibers. J Phys Chem B 110:7178–7183CrossRefGoogle Scholar
  17. 17.
    Zhu X, Zhu Y, Murali S, Stoller MD, Ruoff RS (2011) Nanostructured reduced graphene oxide/Fe2O3 composite as a high-performance anode material for lithium ion batteries. ACS Nano 5:3333–3338CrossRefGoogle Scholar
  18. 18.
    Ji L, Tan Z, Kuykendall TR, Aloni S, Xun S, Lin E, Battaglia V, Zhang Y (2011) Fe3O4 nanoparticle-integrated graphene sheets for high-performance half and full lithium ion cells. Phys Chem Chem Phys 13:7170–7177CrossRefGoogle Scholar
  19. 19.
    Xue X-Y, Ma C-H, Cui C-X, Xing L-L (2011) High lithium storage performance of α-Fe2O3/graphene nanocomposites as lithium-ion battery anodes. Solid State Sci 13:1526–1530CrossRefGoogle Scholar
  20. 20.
    Han S-W, Jung D-W, Jeong J-H, Oh E-S (2012) Effects of VGCF pretreatment on the characteristics of Fe2O3/VGCF composites as anode materials for Li-ion batteries. J Appl Electrochem 42:1057–1064CrossRefGoogle Scholar
  21. 21.
    Kim KH, Jung DW, Pham VH, Chung JS, Kong BS, Lee JK, Kim K, Oh ES (2012) Performance enhancement of Li-ion batteries by the addition of metal oxides (CuO, Co3O4)/solvothermally reduced graphene oxide composites. Electrochim Acta 69:358–363CrossRefGoogle Scholar
  22. 22.
    Jeong J-H, Jung D-W, Han S-W, Kim K-H, Oh E-S (2011) Performance of nanosized Fe3O4 and CuO supported on graphene as anode materials for lithium ion batteries. J Korean Electrochem Soc 14:239–244CrossRefGoogle Scholar
  23. 23.
    Pierard N, Fonseca A, Colomer J-F, Bossuot C, Benoit J-M, Tendeloo GV, Pirard J-P, Nagy JB (2004) Ball milling effect on the structure of single-wall carbon nanotubes. Carbon 42:1691–1697CrossRefGoogle Scholar
  24. 24.
    Ma J, Wang JN (2008) Purification of single-walled carbon nanotubes by a highly efficient and nondestructive approach. Chem Mater 20:2895–2902CrossRefGoogle Scholar
  25. 25.
    Tulevski GS, Hannon J, Afzali A, Chem Z, Avouris P, Kagan CR (2007) Chemically assisted directed assembly of carbon nanotubes for the fabrication of large-scale device arrays. J Am Chem Soc 129:11964–11968CrossRefGoogle Scholar
  26. 26.
    Hai C, Fuji M, Watanabe H, Wang F, Shirai T, Takahashi M (2011) Evaluation of surfactant-free stabilized vapor grown carbon fibers with ζ-potential and Raman spectroscopy. Colloids Surf A 381:70–73CrossRefGoogle Scholar
  27. 27.
    Zhang M, Qu B, Lei D, Chen Y, Yu X, Chen L, Li Q, Wang Y, Wang T (2012) A green and fast strategy for the scalable synthesis of Fe2O3/graphene with significantly enhanced Li-ion storage properties. J Mater Chem 22:3868–3874CrossRefGoogle Scholar
  28. 28.
    Song YQ, Qin SS, Zhang YW, Gao WQ, Liu JP (2010) Large-scale porous hematite nanorod arrays: direct growth on titanium foil and reversible lithium storage. J Phys Chem C 114:21158–21164CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media Dordrecht 2015

Authors and Affiliations

  1. 1.School of Chemical EngineeringUniversity of UlsanUlsanRepublic of Korea

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