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A glassy carbon electrode modified by a copolymer of Co-tetrakis (para-aminophenyl)porphyrin and ortho-phenylenediamine. Characterization and electrocatalytic sulfite oxidation behavior of a basic extract from red wine

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Abstract

In this work, we present a comparison among three glassy carbon electrodes modified by Co-porphyrin, ortho-phenylenediamine, or both simultaneously. This comparison shows the differences among the electrochemical behavior, morphological characteristics and electrocatalytic behavior toward the sulfite oxidation of these electrodes. The electrode modified by Co-porphyrin, ortho-phenylenediamine and copolymer has been investigated in detail for the comparision of electrocatalytic activity towards the sulfite oxidation. In the case of the glassy carbon-modified electrodes, the presence of the copolymer enhances the electrocatalytic performance of the modified electrodes in spite of the non-catalytic response (compared to the bare glassy carbon) of both homopolymer-modified electrodes toward the oxidation of sulfite. Additionally, the oxidation of sulfite extracted from red wine is shown. The copolymer-modified electrode is capable of oxidizing the extracted free sulfite in a 0.02 M NaOH solution. Through the addition of standards method, a concentration of free sulfite in a Chilean red wine sample was determined to be 44 ppm.

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Acknowledgments

Financial support from Fondecyt-Postdoctoral 3130594 and 1120071 Fondecyt-Regular projects. This study has been supported by Project ICM-P10-003-F, CILIS, granted by Fondo de Innovación para la Competitividad, del Ministerio de Economía, Fomento y Turismo, Chile.

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Authors and Affiliations

  1. Department of Chemical Engineering, Laboratory of Membrane Separation Processes–LabProSeM, University of Santiago de Chile, Av. B. O’Higgins 3363, Estación Central, Santiago, Chile

    Roxana Arce & Julio Romero

  2. Department of Chemistry of the Materials, Laboratory of Conducting Polymers, University of Santiago de Chile, Av. B. O’Higgins 3363, Estación Central, Santiago, Chile

    María J. Aguirre

Authors
  1. Roxana Arce
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  2. Julio Romero
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  3. María J. Aguirre
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Correspondence to Roxana Arce.

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Arce, R., Romero, J. & Aguirre, M.J. A glassy carbon electrode modified by a copolymer of Co-tetrakis (para-aminophenyl)porphyrin and ortho-phenylenediamine. Characterization and electrocatalytic sulfite oxidation behavior of a basic extract from red wine. J Appl Electrochem 44, 1361–1369 (2014). https://doi.org/10.1007/s10800-014-0750-7

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  • DOI: https://doi.org/10.1007/s10800-014-0750-7

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