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Journal of Applied Electrochemistry

, Volume 44, Issue 2, pp 337–344 | Cite as

Poly(crystal violet)/graphene-modified electrode for the simultaneous determination of trace lead and cadmium ions in water samples

  • Meifeng Chen
  • Mingyong ChaoEmail author
  • Xinying Ma
Research Article

Abstract

A novel poly(crystal violet)/graphene-modified glassy carbon electrode (PCV/Gr/GCE) was fabricated for the simultaneous determination of Pb2+ and Cd2+. The electrochemical behavior of both species at the PCV/Gr/GCE was investigated employing cyclic voltammetry. In acetate buffer, the modified electrode showed an excellent electrocatalytical effect on the oxidation of both species and was further used for their determination. Under optimized analytical conditions, the oxidation peak currents of Pb2+ and Cd2+ obtained by differential pulse voltammetry in pH 4.6 acetate buffer showed a linear relationship with their concentrations in the ranges of 2.00 × 10−8–1.95 × 10−5 mol L−1 and 4.00 × 10−8–5.58 × 10−5 mol L−1, respectively. The developed method has excellent sensitivity, selectivity, reproducibility and has been successfully applied to the determination of Pb2+ and Cd2+ in water samples.

Keywords

Poly(crystal violet)/graphene-modified electrode Lead and cadmium Cyclic voltammetry Differential pulse voltammetry 

Notes

Acknowledgments

This work was financially supported by a project of Shandong Province Higher Educational Science and Technology Program (J12LD53) and Heze University Scientific Research Fund (XY12BS07).

References

  1. 1.
    Korzun EA, Heck HH (1990) Sources and fates of lead and cadmium in municipal solid waste. J Air Waste Manage Assoc 40:1220–1226CrossRefGoogle Scholar
  2. 2.
    Rodríguez Martín JA, Arias ML, Grau Corbí JM (2006) Heavy metals contents in agricultural topsoils in the Ebro basin (Spain). Application of the multivariate geoestatistical methods to study spatial variations. Environ Pollut 144:1001–1012CrossRefGoogle Scholar
  3. 3.
    Siddiqui S (2012) Lead induced genotoxicity in Vigna mungo var. HD-94. J Saudi Soc Agric Sci 11:107–112Google Scholar
  4. 4.
    Mdl Vázquez-Sauceda, Pérez-Castañeda R, Sánchez-Martínez J, Aguirre-Guzmán G (2012) Cadmium and lead levels along the estuarine ecosystem of Tigre River-San Andres Lagoon, Tamaulipas, Mexico. Bull Environ Contam Toxicol 89:782–785CrossRefGoogle Scholar
  5. 5.
    Hartwig A (1994) Role of DNA repair inhibition in lead- and cadmium-induced genotoxicity: a review. Environ Health Perspect 102:45–50Google Scholar
  6. 6.
    Li H, Li J, Yang Z, Xu Q, Hou C, Peng J, Hu X (2011) Simultaneous determination of ultratrace lead and cadmium by square wave stripping voltammetry with in situ depositing bismuth at nafion-medical stone doped disposable electrode. J Hazard Mater 191:26–31CrossRefGoogle Scholar
  7. 7.
    Ma X, Chao M, Chen M (2013) Simultaneous electrochemical determination of norepinephrine, ascorbic acid and uric acid using a graphene modified glassy carbon electrode. Russ J Electrochem. doi: 10.1134/s1023193513050108
  8. 8.
    Ma X, Chao M, Wang Z (2012) Electrochemical detection of dopamine in the presence of epinephrine, uric acid and ascorbic acid using a graphene-modified electrode. Anal Methods 4:1687–1692CrossRefGoogle Scholar
  9. 9.
    Ma X, Chao M, Wang Z (2013) Electrochemical determination of Sudan I in food samples at graphene modified glassy carbon electrode based on the enhancement effect of sodium dodecyl sulphonate. Food Chem 138:739–744CrossRefGoogle Scholar
  10. 10.
    Philips MF, Gopalan AI, Lee K-P (2012) Development of a novel cyano group containing electrochemically deposited polymer film for ultrasensitive simultaneous detection of trace level cadmium and lead. J Hazard Mater 237:46–54CrossRefGoogle Scholar
  11. 11.
    Teixeira Tarley CR, Santos VS, Lobo Baeta BE, Pereira AC, Kubota LT (2009) Simultaneous determination of zinc, cadmium and lead in environmental water samples by potentiometric stripping analysis (PSA) using multiwalled carbon nanotube electrode. J Hazard Mater 169:256–262CrossRefGoogle Scholar
  12. 12.
    Andersen NPR (1998) Limitations of the use of the electrochemical quartz crystal microbalance in stripping analysis of lead(II) and cadmium(II) on a quartz crystal platinum electrode with a thin mercury film. Anal Chim Acta 368:191–196CrossRefGoogle Scholar
  13. 13.
    de Carvalho LM, do Nasciniento PC, Koschinsky A, Bau M, Stefanello RF, Spengler C, Bohrer D, Jost C (2007) Simultaneous determination of cadmium, lead, copper, and thallium in highly saline samples by anodic stripping voltammetry (ASV) using mercury-film and bismuth-film electrodes. Electroanalysis 19:1719–1726Google Scholar
  14. 14.
    de Oliveira MF, Saczk AA, Okumura LL, Fernandes AP, de Moraes M, Stradiotto NR (2004) Simultaneous determination of zinc, copper, lead, and cadmium in fuel ethanol by anodic stripping voltammetry using a glassy carbon–mercury-film electrode. Anal Bioanal Chem 380:135–140CrossRefGoogle Scholar
  15. 15.
    Fischer E, van den Berg CMG (1999) Anodic stripping voltammetry of lead and cadmium using a mercury film electrode and thiocyanate. Anal Chim Acta 385:273–280CrossRefGoogle Scholar
  16. 16.
    Lam MT, Murimboh J, Hassan NM, Chakrabarti CL (2001) Kinetic speciation of lead and cadmium in freshwaters using square-wave anodic stripping voltammetry with a thin mercury film rotating disk electrode. Electroanalysis 13:94–99CrossRefGoogle Scholar
  17. 17.
    Macca C, Bradshaw M, Merkoci A, Scollary G (1997) Stripping potentiometry of lead, cadmium and copper at a nafion coated glassy carbon electrode with encapsulated mercury acetate. Anal Lett 30:1223–1234CrossRefGoogle Scholar
  18. 18.
    Murimboh J, Lam MT, Hassan NM, Chakrabarti CL (2000) A study of nafion-coated and uncoated thin mercury film-rotating disk electrodes for cadmium and lead speciation in model solutions of fulvic acid. Anal Chim Acta 423:115–126CrossRefGoogle Scholar
  19. 19.
    Nagles E, Arancibia V, Rios R (2012) Determination of lead and cadmium in the presence of quercetin-5′-sulfonic acid by adsorptive stripping voltammetry with a hanging mercury drop electrode and a nafion-coated mercury film electrode. Int J Electrochem Sci 7:4545–4558Google Scholar
  20. 20.
    Nagles E, Arancibia V, Rios R, Rojas C (2012) Simultaneous determination of lead and cadmium in the presence of morin by adsorptive stripping voltammetry with a nafion-ionic liquid-coated mercury film electrode. Int J Electrochem Sci 7:5521–5533Google Scholar
  21. 21.
    Nagles E, Arancibia V, Rojas C, Segura R (2012) Nafion-mercury coated film electrode for the adsorptive stripping voltammetric determination of lead and cadmium in the presence of pyrogallol red. Talanta 99:119–124CrossRefGoogle Scholar
  22. 22.
    Prabakar SJR, Sakthivel C, Narayanan SS (2011) Hg(II) immobilized MWCNT graphite electrode for the anodic stripping voltammetric determination of lead and cadmium. Talanta 85:290–297CrossRefGoogle Scholar
  23. 23.
    Sherigara BS, Shivaraj Y, Mascarenhas RJ, Satpati AK (2007) Simultaneous determination of lead, copper and cadmium onto mercury film supported on wax impregnated carbon paste electrode—assessment of quantification procedures by anodic stripping voltammetry. Electrochim Acta 52:3137–3142CrossRefGoogle Scholar
  24. 24.
    Armstrong KC, Tatum CE, Dansby-Sparks RN, Chambers JQ, Xue Z-L (2010) Individual and simultaneous determination of lead, cadmium, and zinc by anodic stripping voltammetry at a bismuth bulk electrode. Talanta 82:675–680CrossRefGoogle Scholar
  25. 25.
    Bi Z, Chapman CS, Salauen P, van den Berg CMG (2010) Determination of lead and cadmium in sea- and freshwater by anodic stripping voltammetry with a vibrating bismuth electrode. Electroanalysis 22:2897–2907CrossRefGoogle Scholar
  26. 26.
    Hwang G-H, Han W-K, Hong S-J, Park J-S, Kang S-G (2009) Determination of trace amounts of lead and cadmium using a bismuth/glassy carbon composite electrode. Talanta 77:1432–1436CrossRefGoogle Scholar
  27. 27.
    Kachoosangi RT, Banks CE, Ji X, Compton RG (2007) Electroanalytical determination of cadmium(II) and lead(II) using an in situ bismuth film modified edge plane pyrolytic graphite electrode. Anal Sci 23:283–289CrossRefGoogle Scholar
  28. 28.
    Kadara RO, Tothill IE (2008) Development of disposable bulk-modified screen-printed electrode based on bismuth oxide for stripping chronopotentiometric analysis of lead(II) and cadmium(II) in soil and water samples. Anal Chim Acta 623:76–81CrossRefGoogle Scholar
  29. 29.
    Lee G-J, Kim CK, Lee MK, Rhee CK (2010) Advanced use of nanobismuth/nafion electrode for trace analyses of zinc, cadmium, and lead. J Electrochem Soc 157:J241–J244CrossRefGoogle Scholar
  30. 30.
    Liu B, Lu L, Wang M, Zi Y (2008) A study of nafion-coated bismuth-film electrode for the determination of zinc, lead, and cadmium in blood samples. Electroanalysis 20:2363–2369CrossRefGoogle Scholar
  31. 31.
    Siriangkhawut W, Pencharee S, Grudpan K, Jakmunee J (2009) Sequential injection monosegmented flow voltammetric determination of cadmium and lead using a bismuth film working electrode. Talanta 79:1118–1124CrossRefGoogle Scholar
  32. 32.
    Toghill KE, Wildgoose GG, Moshar A, Mulcahy C, Compton RG (2008) The fabrication and characterization of a bismuth nanoparticle modified boron doped diamond electrode and its application to the simultaneous determination of cadmium(II) and lead(II). Electroanalysis 20:1731–1737CrossRefGoogle Scholar
  33. 33.
    Wonsawat W, Dungchai W, Motomizu S, Chuanuwatanakul S, Chailapakul O (2012) Highly sensitive determination of cadmium and lead using a low-cost electrochemical flow-through cell based on a carbon paste electrode. Anal Sci 28:141–146CrossRefGoogle Scholar
  34. 34.
    Xu H, Zeng L-P, Xing S-J, Xian Y-Z, Jin L-T (2008) Nafion-coated bismuth film electrodes for the determination of trace lead and cadmium in herbal medicines by anodic stripping voltammetry. Chin J Chem 26:847–853CrossRefGoogle Scholar
  35. 35.
    Wonsawat W, Chuanuwatanakul S, Dungchai W, Punrat E, Motomizu S, Chailapakul O (2012) Graphene–carbon paste electrode for cadmium and lead ion monitoring in a flow-based system. Talanta 100:282–289CrossRefGoogle Scholar
  36. 36.
    Nguyen PKQ, Lunsford SK (2012) Electrochemical response of carbon paste electrode modified with mixture of titanium dioxide/zirconium dioxide in the detection of heavy metals: lead and cadmium. Talanta 101:110–121CrossRefGoogle Scholar
  37. 37.
    de Oliveira PR, Stradiotto NR, Tanaka AA, Bergamini MF (2012) Anodic stripping voltammetric determination of lead(II) and cadmium(II) by using a carbon nanotubes paste electrode modified with ion exchange synthetic resin. Curr Anal Chem 8:520–527CrossRefGoogle Scholar
  38. 38.
    Minh-Phuong Ngoc B, Li CA, Han KN, Xuan-Hung P, Seong GH (2012) Electrochemical determination of cadmium and lead on pristine single-walled carbon nanotube electrodes. Anal Sci 28:699–704CrossRefGoogle Scholar
  39. 39.
    Beltagi AM, Ghoneim EM, Ghoneim MM (2011) Simultaneous determination of cadmium(II), lead(II), copper(II) and mercury(II) by square-wave anodic stripping voltammetry at a montmorillonite-calcium modified carbon paste electrode. Int J Environ Anal Chem 91:17–32CrossRefGoogle Scholar
  40. 40.
    Wang Z, Liu E, Zhao X (2011) Glassy carbon electrode modified by conductive polyaniline coating for determination of trace lead and cadmium ions in acetate buffer solution. Thin Solid Films 519:5285–5289CrossRefGoogle Scholar
  41. 41.
    Novoselov KS, Geim AK, Morozov SV, Jiang D, Zhang Y, Dubonos SV, Grigorieva IV, Firsov AA (2004) Electric field effect in atomically thin carbon films. Science 306:666–669CrossRefGoogle Scholar
  42. 42.
    Ameen S, Akhtar MS, Shin HS (2012) Hydrazine chemical sensing by modified electrode based on in situ electrochemically synthesized polyaniline/graphene composite thin film. Sens Actuators B Chem 173:177–183CrossRefGoogle Scholar
  43. 43.
    Tian J, Zhao H, Zhao H, Quan X (2012) Photoelectrochemical immunoassay for microcystin-LR based on a fluorine-doped tin oxide glass electrode modified with a CdS–graphene composite. Microchim Acta 179:163–170CrossRefGoogle Scholar
  44. 44.
    Wu T, Cai X, Tan S, Li H, Liu J, Yang W (2011) Adsorption characteristics of acrylonitrile, p-toluenesulfonic acid, 1-naphthalenesulfonic acid and methyl blue on graphene in aqueous solutions. Chem Eng J 173:144–149CrossRefGoogle Scholar
  45. 45.
    Chao M, Ma X, Li X (2012) Graphene-modified electrode for the selective determination of uric acid under coexistence of dopamine and ascorbic acid. Int J Electrochem Sci 7:2201–2213Google Scholar

Copyright information

© Springer Science+Business Media Dordrecht 2013

Authors and Affiliations

  1. 1.Department of Chemistry and Chemical EngineeringHeze UniversityHezePeople’s Republic of China

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