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Performance of internal reforming methanol fuel cell under various methanol/water concentrations

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Abstract

Copper-based reforming catalyst was placed adjacent to ADVENT Technologies high-Temperature polymer electrolyte membrane/electrode assembly in a novel internal reforming methanol fuel cell (IRMFC) and tested for their electrochemical properties and chemical stability under various methanol/water anode feedstreams. Polarization measurements and AC impedance spectroscopy combined with measurements of reactor outlet composition were carried out. Methanol is being reformed inside the anode compartment of the fuel cell at 200 °C producing H2, which is readily oxidized at the anode to produce electricity. The reformer provides enough hydrogen supply for efficient fuel cell operation at 600 mV with 0.2 A cm−2 and a hydrogen stoichiometric ratio of 1.2 (λH2 = H2 fed/H2 reacted = 1.2). However, unreacted MeOH (~5 %) in combination with low H2 content poisons the anode electrode and the cell performance rapidly decreases. Gradual recovery of the initial performance under pure H2 is observed after switching to pure H2. A slight improvement of the cell’s design by the introduction of a pre-reforming step significantly improves the electrocatalytic behavior.

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References

  1. Avgouropoulos G, Papavasiliou J, Daletou MK, Kallitsis JK, Ioannides T, Neophytides S (2009) Reforming methanol to electricity in a high temperature PEM fuel cell. Appl Catal B: Environ 90:628–632

    Article  CAS  Google Scholar 

  2. Samms SR, Savinell RF (2002) Kinetics of methanol-steam reformation in an internal reforming fuel cell. J Power Source 112:13–29

    Article  CAS  Google Scholar 

  3. Savinell R, Yeager E, Tryk D, Landau U, Wainwright J, Weng D, Litt M, Rogers C (1994) Polymer electrolyte for operation at temperatures up to 200 °C. J Electrochem Soc 141:46–48

    Article  Google Scholar 

  4. Avgouropoulos G, Ioannides T, Kallitsis JK, Neophytides S (2011) Development of an internal reforming alcohol fuel cell: concept, challenges and opportunities. Chem Eng J 176–177:95–101

    Article  Google Scholar 

  5. Avgouropoulos G, Papavasiliou J, Daletou M, Geormezi M, Triantafyllopoulos N, Ioannides T, Kallitsis J, Neophytides S (2008) Internal reforming alcohol high temperature PEM fuel cell. US Patent 200861/095779

  6. Daletou MK, Gourdoupi N, Kallitsis JK (2005) Proton conducting membranes based on blends of PBI with aromatic polyethers containing pyridine units. J Membr Sci 252:115–122

    Article  CAS  Google Scholar 

  7. Gourdoupi N, Andreopoulou K, Deimede V, Kallitsis JK (2003) Novel proton-conducting polyelectrolyte composed of an aromatic polyether containing main-chain pyridine units for fuel cell applications. Chem Mater 15:5044–5050

    Article  CAS  Google Scholar 

  8. Papavasiliou J, Avgouropoulos G, Ioannides T (2006) In situ combustion synthesis of structured Cu-Ce-O and Cu-Mn-O catalysts for the production and purification of hydrogen. Appl Catal B: Environ 66:168–174

    Article  CAS  Google Scholar 

  9. Papavasiliou J, Avgouropoulos G, Ioannides T (2005) Steam reforming of methanol over copper–manganese spinel oxide catalysts. Catal Commun 6:497–501

    Article  CAS  Google Scholar 

  10. Papavasiliou J, Avgouropoulos G, Ioannides T (2007) Combined steam reforming of methanol over Cu–Mn spinel oxide catalysts. J Catal 251:7–20

    Article  CAS  Google Scholar 

  11. Papavasiliou J, Avgouropoulos G, Ioannides T (2012) CuMnOx catalysts for internal reforming methanol fuel cells: application aspects. Int J Hydrogen Energy. doi:10.1016/j.ijhydene.2012.02.124

    Google Scholar 

  12. Papadimitriou KD, Paloukis F, Neophytides SG, Kallitsis JK (2011) Cross-linking of side chain unsaturated aromatic polyethers for high temperature polymer electrolyte membrane fuel cell applications. Macromolecules 44:4942–4951

    Article  CAS  Google Scholar 

  13. Katsaounis A, Balomenou S, Tsiplakides D, Brosda S, Neophytides S, Vayenas CG (2005) Proton tunneling-induced bistability, oscillations and enhanced performance of PEM fuel cells. Appl Catal B: Environ 56:251–258

    Article  CAS  Google Scholar 

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Acknowledgments

Financial support from The Fuel Cells and Hydrogen Joint Undertaking (FCH JU; Area SP1-JTI-FCH-2009.4.2; Grant agreement No. 245202) is gratefully acknowledged.

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Authors and Affiliations

  1. FORTH/ICE-HT, Stadiou Street, Platani, P.O. Box 1414, 26504, Patras, Greece

    G. Avgouropoulos & S. G. Neophytides

  2. Department of Materials Science, University of Patras, 26504, Rio Patras, Greece

    G. Avgouropoulos

  3. Advent Technologies SA, Patras Science Park, Stadiou Street, 26504, Platani, Greece

    S. G. Neophytides

Authors
  1. G. Avgouropoulos
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  2. S. G. Neophytides
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Correspondence to G. Avgouropoulos.

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Avgouropoulos, G., Neophytides, S.G. Performance of internal reforming methanol fuel cell under various methanol/water concentrations. J Appl Electrochem 42, 719–726 (2012). https://doi.org/10.1007/s10800-012-0453-x

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  • DOI: https://doi.org/10.1007/s10800-012-0453-x

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