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Effect of lithium difluoro(oxalate)borate (LiDFOB) additive on the performance of high-voltage lithium-ion batteries

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Abstract

Lithium difluoro(oxalato)borate (LiDFOB) was investigated as an electrolyte additive for high-voltage lithium-ion batteries in order to decrease the decomposition of the electrolyte. As a typical high-voltage cathode material, LiCoPO4 was tested in the LiDFOB-containing electrolyte, exhibiting higher reversible charge/discharge capacity and better cyclic stability. The effect of LiDFOB on the formation of a stable interphase film was investigated through cyclic voltammetry and X-ray photoelectron spectroscopy. LiDFOB was helpful to form a stable interphase film and passivate the cathode surface; therefore, the decomposition of the electrolyte was inhibited accordingly.

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Authors and Affiliations

  1. Nankai University, Tianjin, People’s Republic of China

    Meng Hu, Jinping Wei, Liying Xing & Zhen Zhou

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  1. Meng Hu
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  2. Jinping Wei
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  3. Liying Xing
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  4. Zhen Zhou
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Correspondence to Jinping Wei or Zhen Zhou.

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Hu, M., Wei, J., Xing, L. et al. Effect of lithium difluoro(oxalate)borate (LiDFOB) additive on the performance of high-voltage lithium-ion batteries. J Appl Electrochem 42, 291–296 (2012). https://doi.org/10.1007/s10800-012-0398-0

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  • DOI: https://doi.org/10.1007/s10800-012-0398-0

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