Abstract
A sensitive amperometric hydrogen peroxide (HP) sensor was constructed based on silver nanoparticles/poly(2-(N-morpholine) ethane sulfonic acid) (PMES) modified glassy carbon electrode. PMES and silver nanoparticles were orderly introduced to the surface of the electrode by electrochemical methods and characterized by cyclic voltammetry, scanning electron microscopy, and X-ray powder diffraction. The fabricated electrode showed a good electrocatalytic activity toward the reduction of HP with a line range from 0.6 μM to 0.54 mM and a detection limit of 0.18 μM. In addition, the sensor exhibited favorable reproducibility and good long-term stability, and was applied to determine HP in real sample with satisfactory result.
Similar content being viewed by others
References
Hurdis EC, Romeyn JH (1954) Anal Chem 26:320
Hanaoka S, Lin JM, Yamada M (2001) Anal Chim Acta 426:57
Nakashima K, Maki K, Kawaguchi S et al (1991) Anal Sci 7:709
Wu YC, Thangamuthu R, Chen SM (2009) Electroanalysis 2:210
Liu Y, Chu ZY, Jin WQ (2009) Electrochem Commun 11:484
Qin XY, Lu WB, Luo YL et al (2011) Electrochem Commun 13:785
Shobha Jeykumari DR, Ramaprabhu S et al (2007) Carbon 45:1340
Shi AW, Qu FL, Yang MH et al (2008) Sens Actuators B 129:779
Lu WB, Luo YL, Chang G et al (2011) Thin Solid Films 520:554
Liu S, Wang L, Tian JQ et al (2011) J Colloid Interf Sci 363:615
Patel AC, Li S, Yuan JM et al (2006) Nano Lett 6:1042
Feng JJ, Xu JJ, Chen HY (2007) Biosens Bioelectron 22:1618
Hasebe Y, Gu T (2005) J Electroanal Chem 576:177
Batchelor-McAuley C, Du Y, Wildgoose GG et al (2008) Sens Actuators B 135:230
Zhao B, Liu ZR, Liu ZL et al (2009) Electrochem Commun 11:1707
Lu WB, Luo YL, Chang G et al (2011) Biosens Bioelectron 26:4791
Liu S, Tian JQ, Zhai JF et al (2011) Analyst 136:20
Sun T, Seff K (1994) Chem Rev 94:857
Lu WB, Chang G, Luo YL et al (2011) J Mater Sci 46:5260
Lu WB, Liao F, Luo YL et al (2011) Electrochim Acta 56:2295
Tian JQ, Li HL, Lu WB et al (2011) Analyst 136:1806
Cui K, Song YH, Yao Y et al (2008) Electrochem Commun 10:663
Liu S, Tian JQ, Wang L et al (2011) Carbon 49:3158
Chang G, Lu WB, Liao F et al (2011) J Nanopart Res 13:2689
Balamurugan A, Chen SM (2009) Electroanalysis 21:1419
Zhao W, Wang HC, Qin X et al (2009) Talanta 80:1029
Wu S, Zhao HT, Ju HX et al (2006) Electrochem Commun 8:1197
Liu CY, Hu JM (2009) Biosens Bioelectron 24:2149
Luo YL, Lu WB, Chang G et al (2011) Electrochim Acta 56:8371
Doblhofer K (1980) Electrochim Acta 25:871
Su WY, Cheng SH (2008) Electrochem Commun 10:899
Lin XQ, Kang GF, Lu LP (2007) Bioelectrochemistry 70:235
Dai ZH, Liu FX, Lu GF et al (2008) J Solid State Electrochem 12:175
Tang H, Hu GZ, Jiang SX et al (2010) J Appl Electrochem 39:2323
Li XM, Xia JP, Zhang SS (2008) Anal Chim Acta 622:104
Singh K, RMd Aminur, Son JI et al (2008) Biosens Bioelectron 23:1595
Chiu JY, Yu CM, Yen MJ et al (2009) Biosens Bioelectron 24:2015
Gao FX, Yuan R, Chai YQ et al (2007) J Biochem Biophys Methods 70:407
Zhang KY, Zhang N, Zhang L et al (2011) Microchim Acta 173:135
Feng XM, Liu YY, Kong QC et al (2010) J Solid State Electrochem 14:923
Acknowledgments
This project was supported by the Opening Project of Anhui Key Laboratory of Spin Electron and Nanomaterials (Cultivating Base) (No. 2010YKF08, No. 2010YKF09, No. 2010YKF06, No. 2011YKF01).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Zhang, K., Zhang, N., Xu, J. et al. Silver nanoparticles/poly(2-(N-morpholine) ethane sulfonic acid) modified electrode for electrocatalytic sensing of hydrogen peroxide. J Appl Electrochem 41, 1419–1423 (2011). https://doi.org/10.1007/s10800-011-0364-2
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10800-011-0364-2