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Adsorption properties and inhibition of mild steel corrosion in hydrochloric acid solution by ceftobiprole

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Abstract

The inhibition effect of ceftobiprole against the corrosion of mild steel in 1 M HCl solution was studied by weight loss, electrochemical impedance spectroscopy (EIS), potentiodynamic polarization and atomic force microscopy techniques. Inhibition efficiency increased with inhibitor concentration where as decreased with acid concentration. Data obtained from EIS studies were analyzed to model the corrosion inhibition process through appropriate equivalent circuit models. The adsorption of ceftobiprole obeyed Langmuir adsorption isotherm. Both thermodynamic and activation parameters were calculated and discussed. Polarization curves indicated that they are mixed type of inhibitors. Polarization curves showed that ceftobiprole act as mixed-type inhibitor. The results obtained from weight loss, EIS and Potentiodynamic polarization are in good agreement.

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References

  1. Badr GE (2009) Corros Sci 51:2529

    Article  CAS  Google Scholar 

  2. Ren Y, Luo Y, Zhang K, Zhu G, Tan X (2008) Corros Sci 50:3147

    Article  CAS  Google Scholar 

  3. Jacob KS, Parameswaran G (2009) Corros Sci. doi:10.1016/j.corsci.2009.09.007

  4. Abd El-Maksoud SA, Fouda AS (2005) Mater Chem Phys 93:84

    Article  CAS  Google Scholar 

  5. Ju H, Kai ZP, Li Y (2008) Corros Sci 50:865

    Article  CAS  Google Scholar 

  6. Mu G, Li X (2005) J Colloid Interface Sci 289:184

    Article  CAS  Google Scholar 

  7. Oguzie EE, Li Y, Wang FH (2007) J Colloid Interface Sci 310:90

    Article  CAS  Google Scholar 

  8. Lece HD, Emregul KC, Atakol O (2008) Corros Sci 50:1460

    Article  CAS  Google Scholar 

  9. Morad MS, Kamal El-Dean AM (2006) Corros Sci 48:3398

    Article  CAS  Google Scholar 

  10. Aljourani J, Raeissi K, Golozar MA (2009) Corros Sci 51:1836

    Article  CAS  Google Scholar 

  11. Lebrini M, Traisnel M, Lagrenee M, Mernari B, Bentiss F (2008) Corros Sci 50:473

    Article  CAS  Google Scholar 

  12. Wanees SAE, Abd El Aal EE (2009) Corros Sci. doi:10.1016/j.corsci.2009.09.022

  13. Damaskin BB, Frumkin AN (1971) In: Hush NS (ed) Adsorption of molecules on electrodes. Wiley-Interscience, London, p 1

    Google Scholar 

  14. Singh AK, Quraishi MA (2009) Corros Sci 51:2752

    Article  CAS  Google Scholar 

  15. Christov M, Popova A (2004) Corros Sci 46:1613

    Article  CAS  Google Scholar 

  16. Fouda AS, Mostarfa HA, El-Taib F, Elewady GY (2005) Corros Sci 47:1988

    Article  CAS  Google Scholar 

  17. Prabhu RA, Shanbhag AV, Venkatesha TV (2007) J Appl Electrochem 37:491

    Article  CAS  Google Scholar 

  18. Li X, Deng S, Fu H, Li T (2009) Electrochim Acta 54:4089

    Article  CAS  Google Scholar 

  19. Moretti G, Guidi F, Grion G (2004) Corros Sci 46:387

    Article  CAS  Google Scholar 

  20. Ferreira ES, Giacomelli C, Giacomelli FC, Spinelli A (2004) Mater Chem Physd 83:129

    Article  CAS  Google Scholar 

  21. Morad MS (2008) Corros Sci 50:436

    Article  CAS  Google Scholar 

  22. Singh AK, Quraishi MA (2009) Corros Sci 52:152

    Article  Google Scholar 

  23. Shukla SK, Singh AK, Ahamad I, Quraishi MA (2009) Mater Lett 63:819

    Article  CAS  Google Scholar 

  24. El-Naggar MM (2007) Corros Sci 49:2226

    Article  CAS  Google Scholar 

  25. Abdallah M (2004) Corros Sci 46:1981

    Article  CAS  Google Scholar 

  26. Obot IB, Obi-Egbedi NO, Umoren SA (2009) Corros Sci 51:1868

    Article  CAS  Google Scholar 

  27. Mathur PB, Vasudevan T (1982) Corrosion 38:171

    CAS  Google Scholar 

  28. Quraishi MA, Ansari FA (2003) J Appl Electrochem 33:233

    Article  CAS  Google Scholar 

  29. Quraishi MA, Ahamad I, Singh AK, Shukla SK, Lal B, Singh V (2008) Mater Chem Phys 112:1035

    Article  CAS  Google Scholar 

  30. Shukla SK, Quraishi MA (2009) Corros Sci 51:1007

    Article  CAS  Google Scholar 

  31. Li XH, Deng SD, Fu H, Mu GN (2008) Corros Sci 50:2635

    Article  CAS  Google Scholar 

  32. Soltani N, Behpour M, Naiemi H (2009) Corros Sci. doi:10.1016/j.corsci.2009.11.045

  33. Szauer T, Brand A (1981) Electrochim Acta 26:1219

    Article  CAS  Google Scholar 

  34. Riggs OL Jr, Hurd RM (1967) Corrosion 23:252

    CAS  Google Scholar 

  35. O’M Bockris J, Drazic D (1962) Electrochim Acta 7:293

    Article  Google Scholar 

  36. Singh AK, Quraishi MA (2010) J Appl Electrochem 40:1293

    Article  CAS  Google Scholar 

  37. Keles H, Keles M, Dehri I, Serindag O (2008) Colloids Surf A 320:138

    Article  CAS  Google Scholar 

  38. Fouda AS, Heakal FE, Radwan MS (2009) J Appl Electrochem 39:391

    Article  CAS  Google Scholar 

  39. Moretti G, Quartarone G, Tassan A, Zingales A (1996) Electrochim Acta 41:1971

    Article  CAS  Google Scholar 

  40. Tang L, Mu G, Liu G (2003) Corros Sci 45:2252

    Article  Google Scholar 

  41. Li X, Deng S, Fu H, Mu G (2009) Corros Sci 51:620

    Article  CAS  Google Scholar 

  42. Tao Z, Zhang S, Li W, Hou B (2009) Corros Sci. doi:10.1016/j.corsci.2009.06.042

  43. Lenderink JW, Linden M, Wit JH (1993) Electrochim Acta 39:1989

    Article  Google Scholar 

  44. Aoki IV, Guedes IG, Maranho SL (2002) J Appl Electrochem 32:915

    Article  CAS  Google Scholar 

  45. Khaled KF (2003) Electrochim Acta 48:2493

    Article  CAS  Google Scholar 

  46. Mahadavian M, Attar MM (2006) Corros Sci 48:4152

    Article  Google Scholar 

  47. Qu Q, Jiang S, Bai W, Li L (2007) Electrochim Acta 52:6811

    Article  CAS  Google Scholar 

  48. Alvarez-Bustamante R, Negrón-Silva G, Abreu-Quijano M, Herrera-Hernández H, Romero-Romo M, Cuán A, Palomar-Pardave M (2009) Electrochim Acta 54:5393

    Article  CAS  Google Scholar 

  49. Lebrini M, Lagrenee M, Vezin H, Traisnel M, Bentiss F (2007) Corros Sci 49:2254

    Article  CAS  Google Scholar 

  50. Hassan HH (2006) Electrochim Acta 51:5966

    Article  CAS  Google Scholar 

  51. Riggs OL Jr (1973) Corrosion inhibitors, 2nd edn. C.C. Nathan, Houston, TX

    Google Scholar 

  52. Singh AK, Quraishi MA (2009) Corros Sci. doi:10.1016/j.corsci.2009.12.011

  53. Khaled KF, Hackerman N (2003) Electrochim Acta 48:2715

    Article  CAS  Google Scholar 

  54. Schweinsberg DP, George GA, Nanayakkara AK, Steiner DA (1988) Corros Sci 28:33

    Article  CAS  Google Scholar 

  55. Shorky H, Yuasa M, Sekine I, Issa RM, El-Baradie HY, Gomma GK (1998) Corros Sci 40:2173

    Article  Google Scholar 

  56. Noor EA (2005) Corros Sci 47:33

    Article  CAS  Google Scholar 

  57. Bentiss F, Jama C, Mernari B, El Attari H, El Kadi L, Lebrini M, Traisnel M, Lagrenee M (2009) Corros Sci 51:1628

    Article  CAS  Google Scholar 

  58. Ali SA, Al-Muallem HA, Rahman SU, Saeed MT (2008) Corros Sci 50:3070

    Article  CAS  Google Scholar 

  59. Lowmunkhong P, Ungthararak D, Sutthivaiyakit P (2009) Corros Sci. doi:10.1016/j.corsci.2009.08.039

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Acknowledgment

One of the author AKS is thankful to University Grant Commission (UGC), New Delhi, for providing Senior Research Fellowship.

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Authors and Affiliations

  1. Department of Applied Chemistry, Institute of Technology, Banaras Hindu University, Varanasi, 221 005, India

    Ashish Kumar Singh & M. A. Quraishi

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  1. Ashish Kumar Singh
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  2. M. A. Quraishi
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Correspondence to M. A. Quraishi.

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Singh, A.K., Quraishi, M.A. Adsorption properties and inhibition of mild steel corrosion in hydrochloric acid solution by ceftobiprole. J Appl Electrochem 41, 7–18 (2011). https://doi.org/10.1007/s10800-010-0202-y

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  • DOI: https://doi.org/10.1007/s10800-010-0202-y

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