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Inhibition by Jasminum nudiflorum Lindl. leaves extract of the corrosion of cold rolled steel in hydrochloric acid solution

Journal of Applied Electrochemistry volume 40, pages 1641–1649 (2010)Cite this article

Abstract

The inhibition effect of Jasminum nudiflorum Lindl. leaves extract (JNLLE) on the corrosion of cold rolled steel (CRS) in 1.0 M hydrochloric acid (HCl) was investigated by weight loss, potentiodynamic polarization, and electrochemical impedance spectroscopy (EIS) methods. The results show that JNLLE acts as a very good inhibitor, and the inhibition efficiency increases with the concentration of JNLLE. The adsorption of JNLLE obeys Langmuir adsorption isotherm. Values of inhibition efficiency obtained from weight loss, potentiodynamic polarization, and electrochemical impedance spectroscopy (EIS) are in good agreement. Polarization curves show that JNLLE behaves as a mixed-type inhibitor in hydrochloric acid. EIS shows that charge-transfer resistance increase and the capacitance of double layer decreases with the inhibitor concentration, confirming the adsorption process mechanism. The adsorbed film on CRS surface containing JNLLE inhibitor was also measured by Fourier transform infrared spectroscopy (FTIR) and scanning electron microscope (SEM). A probable inhibitive mechanism is proposed from the viewpoint of adsorption theory.

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Acknowledgments

This study was carried out in the scope of research project funded by Key Laboratory for Forest Resources Conservation and Use in the Southwest Mountains of China (Southwest Forestry University) Ministry of Education, Key Construction Course of Chemical Engineering for Forest Products of Southwest Forestry University (XKX200907). The electrochemical measurements were carried out using PARSTAT 2273 advanced electrochemical system (Princeton Applied Research) provided by Advanced Science Instrument Sharing Center of Southwest Forestry University.

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Authors and Affiliations

  1. Department of Fundamental Courses, Southwest Forestry University, Kunming, 650224, People’s Republic of China

    Xiang-Hong Li & Hui Fu

  2. Faculty of Wood Science and Decoration Engineering, Southwest Forestry University, Kunming, 650224, People’s Republic of China

    Shu-Duan Deng

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  1. Xiang-Hong Li
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  2. Shu-Duan Deng
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  3. Hui Fu
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Correspondence to Xiang-Hong Li.

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Li, XH., Deng, SD. & Fu, H. Inhibition by Jasminum nudiflorum Lindl. leaves extract of the corrosion of cold rolled steel in hydrochloric acid solution. J Appl Electrochem 40, 1641–1649 (2010). https://doi.org/10.1007/s10800-010-0151-5

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  • DOI: https://doi.org/10.1007/s10800-010-0151-5

Keywords

  • Jasminum nudiflorum Lindl.
  • Corrosion inhibitor
  • Hydrochloric acid
  • Cold rolled steel
  • Polarization
  • EIS
  • FTIR
  • SEM