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Degradation of indole in aqueous solution using contact glow discharge plasma

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Abstract

Exhaustive indole oxidation in aqueous solution was studied using contact glow discharge plasma. The results indicated that the rate of indole degradation increases with the decrease in the solution conductivity. The degradation rate can be enhanced under the following situations. First, the increase in temperature. Second, introduce active carbon and hydrogen peroxide to the solution. Third, the degradation process is performed in alkaline or acidic media rather than the neutral media. Fourth, add Fe2+ to solution to undergo Fenton’s reaction. However, n-butanol was found decelerate the degradation of indole. Some major intermediates produced during the degradation were detected by using both HPLC and GC-MS.

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References

  1. Gregory V, Korshin JK, Gan L (2006) Comparative study of reactions of endocrine disruptors bisphenol A and diethylstilbestrol in electrochemical treatment and chlorination. Water Res 40:1070

    Article  Google Scholar 

  2. Abramov V, Abramov O, Gekhman A, Kuznetsov V, Price GJ (2006) Ultrasonic intensification of ozone and electrochemical destruction of 1, 3-dinitrobenzene and 2, 4-dinitrotoluene. Ult Sonochem 13:303

    CAS  Google Scholar 

  3. Essam T, Amin MA, Tayeb O, Mattiasson B, Guieysse B (2007) Sequential photochemical-biological degradation of chlorophenols. Chemosphere 66:45

    Article  Google Scholar 

  4. Gai K (2006) Aqueous benzoquinone degradation induced by plasma with glow discharge electrolysis, Cana. J Aana Sci Spect 51:181–186

    CAS  Google Scholar 

  5. Sharma AK, Josephson GB, Camaioni DM, Goheen SC (2000) Destruction of pentachlorophenol using glow discharge plasma process. Environ Sci Technol 34:2267–2272

    Article  CAS  Google Scholar 

  6. Sun B, Sato M, Harano A, Clements JS (1998) Non-uniform pulse discharge-induced radical production in distilled water. Environ J Electrostat 43:115–126

    Article  CAS  Google Scholar 

  7. Chen Y, Zhang X, Dai Y, Yuan W (2004) Pulsed high-voltage discharge plasma for degradation of phenol in aqueous solution. Sep Pur Technol 34:5–12

    Article  CAS  Google Scholar 

  8. Sun B, Sato M, Clements JS (2000) Oxidative processes occurring when pulsed high voltage discharge degrade phenol in aqueous solution. Environ Sci Technol 34:509–513

    Article  CAS  Google Scholar 

  9. Sugiarto AT, Ito S, Ohshima T, Sato M, Skalny J (2003) Oxidative decoloration of dyes by pulsed discharge plasma in water. J Electrostat 58:135–145

    Article  CAS  Google Scholar 

  10. Kraft A, Stadelmann M, BlaschkeJ M (2003) Anodic oxidation with doped diamond electrodes: a new advanced oxidation process. Hazard Mater B 103:247–261

    Article  CAS  Google Scholar 

  11. Marselli B, Garacia-Gomez J, Michaud P-A (2003) Electrogeneration of hytroxyl radicals on boron-doped diamond electrodes. J Electrochem Soc 150:D79

    Article  CAS  Google Scholar 

  12. Katsuki N, Takahashi E, Toyoda M, Kurosu T, Iida M, Wakita S, Nishiki Y, Shimamune T (1998) Water electrolysis using diamond thin-film electrodes. J Electrochem Soc 145:2358

    Article  CAS  Google Scholar 

  13. Rodrigo MA, Michaud PA, Duo I (2001) Oxidation of 4-Chlorophenol at boron-doped diamond electrode for wastewater treatment. J Electrochem Soc 148:D60

    Article  CAS  Google Scholar 

  14. Iniesta J, Michaud PA, Panizza M, Cerisola G, Aldaz A, Comninellis C (2001) Electrochemical oxidation of phenol at boron-doped diamond electrode. Electrochem Acta 46:3573

    Article  CAS  Google Scholar 

  15. Malik MA, Ghaffar A, Malik SA (2001) Water purification by electrical discharges. Plasma Sourc Sci Technol 10:82

    Article  CAS  Google Scholar 

  16. Sengupta SK, Singh R, Srivastava AK (1998) A study on non-faradaic yields of anodic contact glow discharge electrolysis using cerous ion as the OH scavenger: an estimate of the primary yield of OH radicals. Indian J Chem 37A:558

    CAS  Google Scholar 

  17. Tezuka M, Iwasaki M (1998) Plasma induced degradation of chlorophenols in an aqueous solution. Thin Solid Films 316:123–127

    Article  CAS  Google Scholar 

  18. Tezuka M, Iwasaki M (2001) Plasma-induced degradation of aniline in aqueous solution. Thin Solid Films 386:204–207

    Article  CAS  Google Scholar 

  19. Grymonpre DR, Sharma AK, Finney WC, Locke BR (2001) The role of Fenton’s reaction in aqueous phase pulsed streamer corona reactors. Chem Eng J 82:189–207

    Article  CAS  Google Scholar 

  20. Gai K, Dong Y (2005) Plasma induced degradation of azobenzene in water. J Chin Chem Soc 52:273–276

    CAS  Google Scholar 

  21. Gai K, Dong Y (2005) Liquid phase auramine oxidation induced by plasma with glow discharge electrolysis. Plasma Sourc Sci Technol 14:589–593

    Article  Google Scholar 

  22. Hase H, Haradar K (2001) Esp detection OH and H radicals generated by contact glow discharge in aqueous. Viva Origino 29:63–65

    CAS  Google Scholar 

  23. Foti G, Gandini D, Comninellis C, Perret A, Haenni W (1999) Electrochem, oxidation of organics by intermediates of water discharge on IrO2 and synthetic diamond anodes. Electrochem Solid State Lett 2:228

    Article  CAS  Google Scholar 

  24. Gai K (2009) Anodic oxidation with platinum electrodes for degradation of p-xylene in aqueous solution. J Electrostat 67:554

    Article  CAS  Google Scholar 

  25. Hickling A, Linacre JK (1954) The anodic oxidation of ferrous sulphate. J Chem Soc 711–719

  26. Dewhurst HA, Flagg JF, Watson PK (1959) Oxidation of aqueous ferrous sulfate by glow discharge. J Electrochem Soc 106:366–367

    Article  CAS  Google Scholar 

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Acknowledgments

We acknowledge the School of GANSU Province Graduate Student Teacher Research Item Project Stake (No. 0910-04).

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Correspondence to Ke Gai.

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Gai, K., Qi, H., Zhang, Y. et al. Degradation of indole in aqueous solution using contact glow discharge plasma. J Appl Electrochem 40, 615–619 (2010). https://doi.org/10.1007/s10800-009-0036-7

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  • DOI: https://doi.org/10.1007/s10800-009-0036-7

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