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Journal of Applied Electrochemistry

, Volume 39, Issue 7, pp 1011–1015 | Cite as

Electrochemical behavior of an inorganic–organic hybrid based on isopolymolybdate anions and ethylenediamine

  • Chunxiang Li
  • Yan Zhang
  • Kevin P. O’Halloran
  • Huiyuan MaEmail author
Original Paper

Abstract

The one-dimensional inorganic–organic compound, (C2H10N2)[Mo3O10], was synthesized hydrothermally, and characterized by single crystal X-ray diffraction. The compound was used as a bulk-modifier to fabricate a renewable three-dimensional chemically modified carbon paste electrode (Mo-CPE) by direct mixing. The electrochemical properties of (C2H10N2)[Mo3O10]-modified Mo-CPE were investigated with respect to their pH-dependence, stability and electrocatalytic activity. The hybrid material bulk modified Mo-CPE not only displays good electrocatalytic activity toward the reduction of BrO3 , IO3 , NO2 and H2O2, but also exhibits good stability and multiple repeatability by simply polishing on the surface of a wet filter paper, a feature which is important for practical applications.

Keywords

Carbon paste electrode Electrochemistry Electrocatalysis Inorganic–organic hybrid 

Notes

Acknowledgements

This work was supported by the National Nature Science Foundation of China (No. 20771031) and the China Postdoctoral Science Foundation (No. 200503644).

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Copyright information

© Springer Science+Business Media B.V. 2009

Authors and Affiliations

  • Chunxiang Li
    • 1
  • Yan Zhang
    • 2
  • Kevin P. O’Halloran
    • 3
  • Huiyuan Ma
    • 1
    Email author
  1. 1.College of Chemistry and Chemical EngineeringHarbin Normal UniversityHarbinPeople’s Republic of China
  2. 2.College of Live and Environmental SciencesCentral University for NationalitiesBeijingPeople’s Republic of China
  3. 3.Department of ChemistryEmory UniversityAtlantaUSA

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