Abstract
The formation of associates in the vapor phase over a mixed oxide is analyzed in relation to the difference in acid-base properties and volatility between its constituent oxides. A method is proposed for assessing the standard enthalpy of formation of gaseous oxy salts. Experimentally determined standard enthalpies of formation are presented for gaseous salts formed by CrO, CrO2, MnO, FeO, CoO, NiO, and MgO.
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Translated from Neorganicheskie Materialy, Vol. 41, No. 12, 2005, pp. 1516–1520.
Original Russian Text Copyright © 2005 by Lopatin, Shugurov, Semenov.
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Lopatin, S.I., Shugurov, S.M. & Semenov, G.A. Gaseous Associates over Oxide Materials. Inorg Mater 41, 1340–1344 (2005). https://doi.org/10.1007/s10789-005-0312-9
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DOI: https://doi.org/10.1007/s10789-005-0312-9