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Stability of the LaCl −4 and LuCl −4 Ions Studied by Mass Spectrometry

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Abstract

The enthalpy stability of the LaCl −4 and LuCl −4 ions is assessed using high-temperature mass spectrometry. The enthalpy of Cl− detachment is determined to be Δr H 0(298.15 K) = 332 ± 10 kJ/mol for LaCl −4 and 359 ± 10 kJ/mol for LuCl −4 .

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Authors and Affiliations

  1. Ivanovo State University of Chemistry and Technology, pr. Engel'sa 7, Ivanovo, 153460, Russia

    L. S. Kudin, D. E. Vorob'ev & V. B. Motalov

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  1. L. S. Kudin
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  2. D. E. Vorob'ev
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  3. V. B. Motalov
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__________

Translated from Neorganicheskie Materialy, Vol. 41, No. 12, 2005, pp. 1510–1515.

Original Russian Text Copyright © 2005 by Kudin, Vorob'ev, Motalov.

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Kudin, L.S., Vorob'ev, D.E. & Motalov, V.B. Stability of the LaCl −4 and LuCl −4 Ions Studied by Mass Spectrometry. Inorg Mater 41, 1334–1339 (2005). https://doi.org/10.1007/s10789-005-0311-x

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  • DOI: https://doi.org/10.1007/s10789-005-0311-x

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