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Preparation and Thermal Transformations of a Hydrous Cadmium Diphosphate Ammine Complex

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Inorganic Materials Aims and scope

Abstract

A solid hydrous cadmium diphosphate ammine complex of composition Cd2P2O7 · 3.0NH3 · 4.5H2O is prepared, and its thermal transformations during constant-rate and quasi-isothermal heating are studied using chemical analysis, paper chromatography, and x-ray diffraction. The results are used to establish the mechanisms of the transformations.

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REFERENCES

  1. Handbuch der praparativen anorganischen Chemie in drei Banden, von Brauer, G., Ed., Stuttgart: Ferdinand Enke, 1978, 3rd ed. Translated under the title Rukovodstvo po neorganicheskomu sintezu, Moscow: Mir, 1985–1986.

    Google Scholar 

  2. Konstant, Z.A. and Dindune, A.P., Fosfaty dvukhvalentnykh metallov (Divalent Metal Phosphates), Riga: Zinatne, 1986.

    Google Scholar 

  3. Garnovskii, A.D., Vasil'chenko, I.S., and Garnovskii, D.A., Sovremennye aspekty sinteza metallokompleksov. Osnovnye ligandy i metody (Modern Technology of Metal Complexes: Major Ligands and Techniques), Rostov-on-Don: LaPo, 2000.

    Google Scholar 

  4. Fornier, M.T. and Capestan, M., Contribution a l'etude du pyrophosphate mercurique. I. Preparation et decomposition thermique a l'air et sous vide du pyrophosphate mercurique. II. Action de l'ammoniac sur Hg2P2O7. Preparations et etude de [Hg(NH3)2]2P2O7, Bull. Soc. Chim. Fr., 1972, vol. 2, pp. 573–576.

    Google Scholar 

  5. Voitenko, L.V., Zhilyak, I.D., and Kopilevich, V.A., Hydrous Ammoniated Cobalt(II) and Nickel(II) Diphosphates Isolated from Aqueous Solutions, Zh. Prikl. Khim. (S.-Peterburg), 2004, vol. 77, no.9, pp. 1421–1424.

    Google Scholar 

  6. Lapina, L.M., Metal Ammonium Phosphates: New Application Areas, Usp. Khim., 1968, vol. 37, no.9, pp. 1626–1641.

    CAS  Google Scholar 

  7. Hogarth, C.A. and Ghauri, M.A., The Electrical Properties of Cadmium Phosphate Glasses at High Electric Fields, J. Mater. Sci., 1980, vol. 15, no.2, pp. 409–414.

    CAS  Google Scholar 

  8. Kopilevich, V.A., Zhilyak, I.D., and Voitenko, L.V., Ukr. Patent 62782, Byull., 2003, no. 12.

  9. Selivanova, G.A. and Kudryavtsev, N.T., Precipitation Conditions and Some Properties of Cadmium Pyrophosphate, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 1972, vol. 15, no.9, pp. 1303–1307.

    CAS  Google Scholar 

  10. Prodan, E.A., Prodan, L.I., and Ermolenko, N.F., Tripolifosfaty i ikh primenenie (Tripolyphosphates and Their Applications), Minsk: Navuka i Tekhnika, 1969.

    Google Scholar 

  11. Umland, F., Janssen, A., Thierig, D., and Wunsch, G., Theorie und praktische Anwendung von Komplexbildnern, Frankfurt am Main: Akademische Verlagsgesellschaft, 1971. Translated under the title Kompleksnye soedineniya v analiticheskoi khimii (Teoriya i praktika primeneniya), Moscow: Mir, 1975.

    Google Scholar 

  12. GOST (State Standard) 20851-75: Mineral Fertilizers, Analytical Techniques, 1983.

  13. Logvinenko, V.A., Paulik, F., and Paulik, J., Kvaziravnovesnaya termogravimetriya v sovremennoi neorganicheskoi khimii (Quasi-equilibrium Thermogravimetry in Modern Inorganic Chemistry), Novosibirsk: Nauka, 1989.

    Google Scholar 

  14. Voitenko, L.V., Kopilevich, V.A., and Shchegrov, L.N., Ammoniated Copper(II), Zinc, and Cobalt(II) Phosphates, Zh. Neorg. Khim., 1992, vol. 37, no.9, pp. 2055–2060.

    CAS  Google Scholar 

  15. Shevchenko, Yu.N., Coordination Compounds of 3d Transition Metals with Borohydride Anions, Extended Abstract of Doctoral (Chem.) Dissertation, Moscow: Kurnakov Inst. of General and Inorganic Chemistry, USSR Acad. Sci., SSSR, 1991.

    Google Scholar 

  16. Kopilevich, V.A., Synthesis and Thermal Transformations of Individual and Nitrogen-Containing Manganese(II), Cobalt(II), Copper(II), and Zinc Phosphates, Extended Abstract of Doctoral (Chem.) Dissertation, Kiev: Inst. of Sorption and Endoecology Problems, Natl. Acad. Sci. Ukr., 1994.

    Google Scholar 

  17. Makatun, V.N., Khimiya neorganicheskikh gidratov (Chemistry of Inorganic Hydrates), Minsk: Nauka i Tekhnika, 1985.

    Google Scholar 

  18. Atlas IK-spektrov fosfatov. Dvoinye mono-i difosfaty (Atlas of IR Spectra of Phosphates: Double Mono-and Diphosphates), Pechkovskii, V.V., Ed., Moscow: Nauka, 1990.

    Google Scholar 

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Authors and Affiliations

  1. National Agrarian University, ul. Generala Rodimtseva 19, Kiev, 03041, Ukraine

    V. A. Kopilevich, I. D. Zhilyak & L. V. Voitenko

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  1. V. A. Kopilevich
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  2. I. D. Zhilyak
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  3. L. V. Voitenko
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__________

Translated from Neorganicheskie Materialy, Vol. 41, No. 12, 2005, pp. 1488–1492.

Original Russian Text Copyright © 2005 by Kopilevich, Zhilyak, Voitenko.

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Kopilevich, V.A., Zhilyak, I.D. & Voitenko, L.V. Preparation and Thermal Transformations of a Hydrous Cadmium Diphosphate Ammine Complex. Inorg Mater 41, 1313–1317 (2005). https://doi.org/10.1007/s10789-005-0308-5

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  • DOI: https://doi.org/10.1007/s10789-005-0308-5

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