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Effect of the Nature of the Metal Solvent on the Vapor-Liquid-Solid Growth Rate of Silicon Whiskers

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Abstract

A relationship is established between the growth rate of silicon whiskers and the solubility of the crystallizing substance in metal solvent particles. The effect of the whisker diameter on the growth rate is analyzed. The solubility of the solid phase is shown to drop as the particle size of the solvent decreases (its specific surface increases). The practical importance of these findings is discussed.

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REFERENCES

  1. Naidich, Yu.V., Kontaktnye yavleniya v metallicheskikh rasplavakh (Contact Phenomena in Metallic Melts), Kiev: Naukova Dumka, 1972.

    Google Scholar 

  2. Adam, N.K., The Physics and Chemistry of Surfaces, London: Oxford Univ. Press, 1941, 3rd ed. Translated under the title Fizika i khimiya poverkhnostei, Moscow: Gostekhizdat, 1947.

    Google Scholar 

  3. Semenchenko, V.K., Poverkhnostnye yavleniya v metallakh i splavakh (Surface Effects in Metals and Alloys), Moscow: Nauka, 1957.

    Google Scholar 

  4. Frolov, Yu.G., Kurs kolloidnoi khimii: Poverkhnostnye yavleniya i dispersnye sistemy (A Course of Colloid Chemistry: Surface Phenomena and Disperse Systems), Moscow: Khimiya, 1989.

    Google Scholar 

  5. Lifshits, I.M. and Slezov, V.V., Diffusion-Controlled Decomposition Kinetics of Supersaturated Solid Solutions, Zh. Eksp. Teor. Fiz., 1958, vol. 35, no.2 (8), pp. 479–492.

    CAS  Google Scholar 

  6. Givargizov, E.I., Rost nitevidnykh i plastinchatykh kristallov iz para (Vapor Growth of Whiskers and Platelike Crystals), Moscow: Nauka, 1977.

    Google Scholar 

  7. Nebol'sin, V.A. and Shchetinin, A.A., Rost nitevidnykh kristallov (Whisker Growth), Voronezh: Voronezh. Gos. Univ., 2003.

    Google Scholar 

  8. Glazov, V.M. and Zemskov, V.S., Fiziko-khimicheskie osnovy legirovaniya poluprovodnikov (Physicochemical Principles of Semiconductor Doping), Moscow: Nauka, 1967.

    Google Scholar 

  9. Weyher, J., Some Notes on the Growth Kinetics and Morphology of VLS Silicon Crystals Grown with Platinum and Gold as Liquid-Forming Agents, J. Cryst. Growth, 1978, vol. 43, no.2, pp. 235–244.

    CAS  Google Scholar 

  10. Voronkov, V.V., Processes at the Solidification Interface, Kristallografiya, 1974, vol. 19, no.6, pp. 922–929.

    CAS  ISI  Google Scholar 

  11. Tatarchenko, V.A., Ustoichivyi rost kristallov (Steady-State Crystal Growth), Moscow: Nauka, 1988.

    Google Scholar 

  12. Koshkin, V.M. and Slezov, V.V., Doping of Nanoparticles, Pis'ma Zh. Tekh. Fiz., 2004, vol. 30, no.9, pp. 38–43.

    Google Scholar 

  13. Nebol'sin, V.A. and Shchetinin, A.A., Role of Surface Energy in the Vapor-Liquid-Solid Growth of Silicon, Neorg. Mater., 2003, vol. 39, no.9, pp. 1050–1055 [Inorg. Mater. (Engl. Transl.), vol. 39, no. 9, pp. 899–903].

    Article  Google Scholar 

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Translated from Neorganicheskie Materialy, Vol. 41, No. 12, 2005, pp. 1425–1428.

Original Russian Text Copyright © 2005 by Nebol'sin, Shchetinin, Dolgachev, Korneeva.

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Nebol'sin, V.A., Shchetinin, A.A., Dolgachev, A.A. et al. Effect of the Nature of the Metal Solvent on the Vapor-Liquid-Solid Growth Rate of Silicon Whiskers. Inorg Mater 41, 1256–1259 (2005). https://doi.org/10.1007/s10789-005-0296-5

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  • DOI: https://doi.org/10.1007/s10789-005-0296-5

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