Abstract
Phase relations in the Nb-Ni-Sb system at 1070 K are studied by x-ray diffraction. The results confirm the existence of the ternary compound Nb28Ni33.5Sb12.5 (new structure type), which is shown to have a narrow homogeneity range. The system contains no solid solutions based on binary compounds, as evidenced by structural analysis data for NiSb and NbSb2 in three-phase Nb-Ni-Sb samples.
Similar content being viewed by others
REFERENCES
Wang, M. and Mar, A., Nb28.5Ni33.5Sb12.5 a New Representative of the x-Phase, J. Solid State Chem., 2001, vol. 160, pp. 450–459.
Akselrud, L.G., Grin, Yu.N., Zavalii, P.Yu., et al., CSD—Universal Program Package for Single Crystal or Powder Structure Data Treatment, 12th Eur. Crystallographic Meet. (Moscow, 1989), Moscow: Nauka, 1989, vol. 3, p. 155.
Okamoto, H., Desk Handbook: Phase Diagrams for Binary Alloys, Metals Park: Am. Soc. for Metals, 2000.
Pearson's Handbook Desk Edition: Crystallographic Data for Intermetallic Phases, Villars, P., Ed., Metals Park: Am. Soc. for Metals, 1997.
Elliott, R.P., Constitution of Binary Alloys, Suppl. no. 1, New York: McGraw-Hill, 1965. Translated under the title Struktury dvoinykh splavov, Moscow: Metallurgiya, 1970.
Rehr, A. and Kauzlarich, S.M., NbSb2, Acta Crystallogr., Sect. C: Cryst. Struct. Commun., 1994, vol. 50, pp. 1177–1178.
Wiberg, N., Lehrbuch der Anorganischen Chemie, New York: Gruyter, 1995, pp. 1838–1840.
Evers, C.B.H., Richter, C.G., Hartjes, K., and Jeitschko, W., Ternary Transition Metal Antimonides and Bismuthides with MgAgAs Type and Filled NiAs-Type Structure, J. Alloys Compd., 1997, vol. 252, pp. 93–97.
Tkizawa, H., Uheda, K., and Endo, T., A New High-Pressure Polymorph of NiSb2, Intermetallics, 2000, vol. 8, pp. 1399–1403.
Pearson, W.B., The Crystal Chemistry and Physics of Metals and Alloys, New York: Wiley, 1972, vol. 1. Translated under the title Kristallokhimiya i fizika metallov i splavov, Moscow: Mir, 1977, vol. 1.
Lomnytska, Ya.F. and Kuz'ma, Yu.B., System Nb-Ni-P, Izv. Akad. Nauk SSSR, Neorg. Mater., 1983, vol. 19, no.8, pp. 1328–1332.
Author information
Authors and Affiliations
Additional information
__________
Translated from Neorganicheskie Materialy, Vol. 41, No. 11, 2005, pp. 1324–1329.
Original Russian Text Copyright © 2005 by Lomnytska, Berezovets.
Rights and permissions
About this article
Cite this article
Lomnytska, Y.F., Berezovets, V.V. Phase Relations in the Nb-Ni-Sb System. Inorg Mater 41, 1166–1171 (2005). https://doi.org/10.1007/s10789-005-0281-z
Received:
Issue Date:
DOI: https://doi.org/10.1007/s10789-005-0281-z