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Vibrational Spectra of Sulfoborate Glasses

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Inorganic Materials Aims and scope

Abstract

The glass-forming regions in the MgSO4-Na2B4O7-K2SO4 and MgSO4-Na2B4O7-KHSO4 systems are shown to lie in the borate-rich corner of the composition triangle and to occupy about 20% of its area. IR and Raman spectroscopy results are used to develop a structural model of the glasses studied. Vibrational spectra suggest that the structure of the glasses is governed by borate glass-forming groups, which incorporate SO4 tetrahedra.

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Authors and Affiliations

  1. Ural State Technical University, ul. Mira 28, Yekaterinburg, 620002, Russia

    V. G. Vyatchina & V. L. Mamoshin

  2. Institute of Solid-State Chemistry, Ural Division, Russian Academy of Sciences, Pervomaiskaya ul. 91, Yekaterinburg, 620219, Russia

    L. A. Perelyaeva, M. G. Zuev & I. V. Baklanova

Authors
  1. V. G. Vyatchina
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  2. L. A. Perelyaeva
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  3. M. G. Zuev
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  4. I. V. Baklanova
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  5. V. L. Mamoshin
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__________

Translated from Neorganicheskie Materialy, Vol. 41, No. 10, 2005, pp. 1277–1279.

Original Russian Text Copyright © 2005 by Vyatchina, Perelyaeva, Zuev, Baklanova, Mamoshin.

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Vyatchina, V.G., Perelyaeva, L.A., Zuev, M.G. et al. Vibrational Spectra of Sulfoborate Glasses. Inorg Mater 41, 1128–1130 (2005). https://doi.org/10.1007/s10789-005-0272-0

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  • DOI: https://doi.org/10.1007/s10789-005-0272-0

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