Abstract
The phase-formation processes in the Bi2O3-M2O3-V2O5 (M = Y, In) systems were investigated. The associated sequence of phase transformations and the conditions for the preparation of phase-pure Bi4V2 − 2x M2x O11 − 2x solid solutions were established. The lattice parameters of the solid solutions were determined, and their conductivity was measured as a function of temperature and composition.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
REFERENCES
Chadwick, A.V., Colli, C., Maltese, C., et al., EXAFS Studies of the Cation Sites in BIMEVOX Fast-Ion Conductors, Solid State Ionics, 1999, vol. 119, nos.1–4, pp. 79–84.
Abraham, F., Boivin, Jc., Mairesse, G., and Nowogrocki, G., The Bimevox Series—A New Family of High Performance Oxide Ion Conductors, Solid State Ionics, 1990, vol. 40/41, pp. 934–937.
Abrahams, I., Krok, F., Bangobango, D., et al., Structural and Electrical Characterization of BINIVOX, Solid State Ionics, 1998, vol. 111, no.1/2, pp. 37–43.
Lasure, S., Vernochet, Ch., Vannier, R.N., et al., Composition Dependence of Oxide Anion Conduction in the BIMEVOX Family, Solid State Ionics, 1996, vol. 90, nos.1–4, pp. 117–123.
Lee, C.K. and Ong, C.S., Synthesis and Characterization of Rare Earth Substituted Bismuth Vanadate Solid Electrolytes, Solid State Ionics, 1999, vol. 117, no.3/4, pp. 301–310.
Prasad, K.V.R., Subbanna, G.N., and Varma, K.B.R., Rare Earth-Substituted Bismuth Vanadate Ceramics, Ferroelectrics, 1995, vol. 166, pp. 223–234.
Osipyan, V.G., Savchenko, L.M., and Elbakyan, V.L., Layered Bismuth Vanadate Ferroelectrics, Izv. Akad. Nauk SSSR, Neorg. Mater., 1987, vol. 23, no.3, pp. 523–525.
Buyanova, E.S., Zhukovskii, V.M., Lopatina, E.S., et al., Synthesis and Electrical Properties of Solid Solutions Based on Bismuth Vanadates, Neorg. Mater., 2002, vol. 38, no.3, pp. 325–330 [Inorg. Mater. (Engl. Transl.), vol. 38, no. 3, pp. 256–260].
Powder Diffraction File, Newtown Square: ICDD, 2000.
Diagrammy sostoyaniya sistem tugoplavkikh oksidov (Phase Diagrams of Refractory Oxide Systems), Leningrad: Nauka, 1986.
Fotiev, A.A., Slobodin, B.V., and Khodos, M.Ya., Vanadaty: Sostav, sintez, struktura, svoistva (Vanadates: Composition, Synthesis, Structure, and Properties), Moscow: Nauka, 1988.
Yremchenko, A.A. and Kharton, V.V., Oxygen Ionic and Electronic Conductivity of La-Doped BIMEVOX, Solid State Ionics, 1998, vol. 111, no.3/4, pp. 227–236.
Lee, C.K. and West, A.R., Thermal Behaviour and Polymorphism of BIMEVOX Oxide Ion Conductors Including the New Materials: Bi4V2O11:M; M = La, Y, Mg, B, Solid State Ionics, 1996, vols. 86–88, pp. 235–239.
Abrahams, I., Krok, F., Nelstrop, I.A.G., and Bogusz, W., Defect Structure of Quenched γ-BINIVOX, Solid State Ionics, 1998, vol. 110, pp. 95–101.
Author information
Authors and Affiliations
Additional information
__________
Translated from Neorganicheskie Materialy, Vol. 41, No. 10, 2005, pp. 1254–1260.
Original Russian Text Copyright © 2005 by Emel'yanova, Salimgareeva, Buyanova, Zhukovskii.
Rights and permissions
About this article
Cite this article
Emel'yanova, Y.V., Salimgareeva, Z.V., Buyanova, E.S. et al. Synthesis and Properties of Bi4V2 − x M2x O11 − 2x (M = Y, In) Solid Solutions. Inorg Mater 41, 1107–1113 (2005). https://doi.org/10.1007/s10789-005-0268-9
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/s10789-005-0268-9