Abstract
The reactions of CaO and Ca(OH)2 with CO2 during mechanical activation are studied by IR spectroscopy, x-ray diffraction, and thermal analysis. The results indicate that the earlier described extensive sorption of CO2 by Ca-containing silicates during grinding is not related to the formation of CaO or Ca(OH)2. Mechanical activation in CO2 converts calcium oxide to amorphous CaCO3 and calcium hydroxide to calcite, whereas Ca-containing silicates under such conditions homogeneously dissolve CO2 to form a material similar to analogous carbonate-containing silicate glasses.
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REFERENCES
Kalinkina, E.V., Kalinkin, A.M., Forsling, W., and Makarov, V.N., Sorption of Atmospheric Carbon Dioxide and Structural Changes of Ca and Mg Silicate Minerals during Grinding, Int. J. Miner. Process., 2001, vol. 61, no.4, pp. 273–299.
Kalinkin, A.M., Politov, A.A., Boldyrev, V.V., et al., Mechanical Activation of Diopside in CO2, Neorg. Mater., 2002, vol. 38, no.2, pp. 215–220 [Inorg. Mater. (Engl. Transl.), vol. 38, no. 2, pp. 163–167].
Kalinkin, A.M., Kalinkina, E.V., and Vasil'eva, T.N., Effect of Mechanical Activation on the Reactivity of Sphene, Kolloidn. Zh., 2004, vol. 66, no.2, pp. 190–197.
Berdonosov, S.S., Berdonosova, G.G., and Znamenskaya, I.V., Industrial Synthesis, Properties, and Practical Applications of Fine-Particle Calcium Carbonate, Khim. Tekhnol., 2002, no. 8, pp. 2–11.
Rashkovich, L.N., Carbonation of Hydrous Calcium Silicates, Stroit. Mater., 1962, no. 6, pp. 31–33.
Butt, Yu.M. and Rashkovich, L.N., Tverdenie vyazhushchikh pri povyshennykh temperaturakh (Hardening of Binders at Elevated Temperatures), Moscow: Izd. Literatury po Stroitel'stvu, 1965.
Poluboyarov, V.A., Avvakumov, E.G., Andrushkova, O.V., et al., Dissociative Processes in Mechanical Activation of Calcium Oxide, Sib. Khim. Zh., 1991, no. 5, pp. 115–122.
Kosova, N.V., Devyatkina, E.T., and Avvakumov, E.G., Mechanochemical Synthesis of Calcium Silicates from Hydrous Oxides, Sib. Khim. Zh., 1992, no. 2, pp. 135–143.
Watanabe, T., Liao, J., and Senna, M., Changes on the Basicity and Species on the Surface of Me(OH)2-SiO2 (Me = Ca, Mg, Sr) Mixtures Due to Mechanical Activation, J. Solid State Chem., 1995, vol. 115, pp. 390–394.
Kosova, N.V., Devyatkina, E.T., and Avvakumov, E.G., Basic and Acidic Surface Centers and Mechanochemical Reactions in Mixtures of Hydrous Oxides, Dokl. Akad. Nauk, 1996, vol. 347, no.4, pp. 489–492.
Avvakumov, E.G. and Pushnyakova, V.A., Mechanochemical Synthesis of Mixed Oxides, Khim. Tekhnol., 2002, no. 5, pp. 6–17.
Zyryanov, V.V., Sysoev, V.F., and Boldyrev, V.V., Mechanochemical Ceramic Technology, Dokl. Akad. Nauk, 1988, vol. 30, no.1, pp. 162–165.
Avvakumov, E.G., Pavlenko, S.I., Kosova, N.V., et al., Composite Binder from Mechanically Activated Industrial Waste, Khim. Interesah Ustoich. Razvit., 2000, no. 8, pp. 657–660.
Karyakin, Yu.V. and Angelov, I.I., Chistye khimicheskie veshchestva (Pure Chemical Substances), Moscow: Khimiya, 1974.
Avvakumov, E.G., Mekhanicheskie metody aktivatsii khimicheskikh protsessov (Mechanical Activation of Chemical Processes), Novosibirsk: Nauka, 1986.
Zyryanov, V.V., Sysoev, V.F., Boldyrev, V.V., and Korosteleva, T.V., USSR Inventor's Certificate no. 1375328, Byull. Izobret., 1988, no. 7, p. 39.
Dymov, A.M., Tekhnicheskii analiz (Technical Analysis), Moscow: Metallurgiya, 1964.
Infrared Spectra of Adsorbed Species, Little, L.H., Ed., New York: Academic, 1967. Translated under the title Infrakrasnye spektry adsorbirovannykh molekul, Moscow: Mir, 1969.
McClellan, A.L. and Harnsberger, H.F., Cross-Sectional Areas of Molecules Adsorbed on Solid Surfaces, J. Colloid Interface Sci., 1967, vol. 23, pp. 577–599.
Fukuda, Y. and Tanabe, K., Infrared Study of Carbon Dioxide Adsorbed on Magnesium and Calcium Oxides, Bull. Chem. Soc. Jpn., 1973, vol. 46, no.6, pp. 1616–1619.
Termicheskie konstanty veshchestv. Spravochnik (Thermal Constants of Substances: A Handbook), Glushko, V.P., Ed., Moscow: VINITI, 1968–1979.
Osin, B.V., Negashenaya izvest' (Unslaked Lime), Gos. Izd. Literatury po Stroimaterialam, 1954.
Yang, T., Keller, B., Magyari, E., et al., Direct Observation of the Carbonation Process on the Surface of Calcium Hydroxide Crystals in Hardened Cement Paste Using an Atomic Force Microscope, J. Mater. Sci., 2003, vol. 38, no.9, pp. 1909–1916.
Koga, N., Nakagoe, Y., and Tanaka, H., Crystallization of Amorphous Calcium Carbonate, Thermochim. Acta, 1998, vol. 318, no.1/2, pp. 239–244.
Sato, M. and Matsuda, S., Structure of Vaterite and Infrared Spectra, Z. Cristallogr., 1969, vol. 129, pp. 405–410.
White, W.B., The Carbonate Minerals, The Infrared Spectra of Minerals, Farmer, V.C., Ed., London: Mineral. Soc., 1974.
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Translated from Neorganicheskie Materialy, Vol. 41, No. 10, 2005, pp. 1218–1224.
Original Russian Text Copyright © 2005 by Kalinkin, Kalinkina, Zalkind, Makarova.
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Kalinkin, A.M., Kalinkina, E.V., Zalkind, O.A. et al. Chemical Interaction of Calcium Oxide and Calcium Hydroxide with CO2 during Mechanical Activation. Inorg Mater 41, 1073–1079 (2005). https://doi.org/10.1007/s10789-005-0263-1
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DOI: https://doi.org/10.1007/s10789-005-0263-1