Abstract
Thermal analysis results indicate that the liquidus surface of the Li2WO4-WO3-Li2B4O7 system consists of the primary phase fields of Li2WO4, Li2B4O7, WO3, Li2WO4 · WO3 (congruent melting), 3Li2WO4 · 2Li2B4O7 (congruent melting), and Li2WO4 · 3WO3 (incongruent melting). Low-melting-point compositions are selected that are potentially attractive for the low-temperature synthesis of lithium tungsten bronze powders.
Similar content being viewed by others
REFERENCES
Ozerov, R.I., Crystal Chemistry of Vanadium, Molybdenum, and Tungsten Oxide Compounds, Usp. Khim., 1955, vol. 2, pp. 951–984.
Shurdumov, B.K., Synthesis of Tungsten Bronze Powders in Ionic Melts: Physicochemical Principles of Optimization, Extended Abstract of Doctoral (Chem.) Dissertation, Nalchik, 2003.
Shurdumov, B.K., Physicochemical Properties of Melts in Systems Containing Alkali-Metal (Sodium and Potassium) Phosphate, Borate, and Chlorides and Tungsten Trioxide, Extended Abstract of Cand. Sci. (Chem.) Dissertation, Novocherkassk, 1975.
Hoerman, F.Z., Anorg. Allg. Chem., 1929, vol. 177, p. 145.
Reau, J.M., Fouassier, G., and Hagenmuller, P., Bull. Soc. Chim. Fr., 1967, no. 10, p. 3873.
Bogodukhova, N.A., Drobasheva, T.I., and Bukhalova, G.A., Complexation in Systems of Lithium, Sodium, and Potassium Tungstates and Tungstic Anhydride, II Vsesoyuznoe soveshchanie po khimii i tekhnologii molibdena i vol'frama (II All-Union Conf. on the Chemistry and Technology of Molybdenum and Tungsten), Nalchik, 1974, p. 45.
Author information
Authors and Affiliations
Additional information
__________
Translated from Neorganicheskie Materialy, Vol. 41, No. 9, 2005, pp. 1116–1118.
Original Russian Text Copyright © 2005 by M. Shurdumov, B. Shurdumov.
Rights and permissions
About this article
Cite this article
Shurdumov, M.B., Shurdumov, B.K. Thermal Analysis of the Ternary System Li2WO4-WO3-Li2B4O7 . Inorg Mater 41, 981–983 (2005). https://doi.org/10.1007/s10789-005-0248-0
Received:
Issue Date:
DOI: https://doi.org/10.1007/s10789-005-0248-0