Abstract
We studied the effect of substrate material on the microstructure and properties of Nb3Sn coatings produced by electrochemical coreduction of Nb and Sn ions in the cathodic zone in molten salts. The results demonstrate that continuous superconducting Nb3Sn coatings can be produced on molybdenum, tantalum, niobium, copper, nickel, Invar and the 60% Ni + 22% Mo + 12% Fe alloy. The coatings grown on molybdenum, tantalum, and niobium have the highest purity. To ensure good superconducting properties of electrodeposited coatings, preference should be given, all other factors being the same, to substrate materials with thermal expansion coefficients close to or smaller than that of Nb3Sn.
Similar content being viewed by others
REFERENCES
Kolosov, V.N., Gel', R.P., and Drobotenko, G.A., Superconducting Properties of Nb-Ta-Sn Coatings Produced by Electrocodeposition, Fiz. Met. Metalloved., 1993, vol. 75, no.6, pp. 69–73.
Kolosov, V.N., Drobotenko, G.A., and Gel', R.P., Effect of Nitrogen on the Structure and Superconducting Properties of Niobium Stannide Produced by Electrocodeposition, Fiz. Met. Metalloved., 1994, vol. 78, no.6, pp. 62–68.
Kolosov, V.N., Effect of Carbon on the Structure and Superconducting Properties of Nb3Sn Coatings Produced by Electrocodeposition, Neorg. Mater., 2004, vol. 40, no.12, pp. 1467–1475 [Inorg. Mater. (Engl. Transl.), vol. 40, no. 12, pp. 1287–1295].
Kolosov, V.N., Drobotenko, G.A., Gel', R.P., and Shatseva, L.S., Distribution of Interstitial Impurities across Nb3Sn Electrolytic Coatings for Microwave Applications, Neorg. Mater., 1998, vol. 34, no.7, pp. 828–832 [Inorg. Mater. (Engl. Transl.), vol. 34, no. 7, pp. 686–690].
Gel', R.P. and Drobotenko, G.A., Behavior of Nickel, Niobium, and Molybdenum in Chloride and Chloride-Fluoride Electrolytes, in Fiziko-khimicheskie i tekhnologicheskie problemy pererabotki syr'ya Kol'skogo poluostrova (Physicochemical and Technological Problems in Kola Peninsula Raw Materials Processing), St. Petersburg: Nauka, 1993, pp. 30–35.
Kolosov, V.N., Matychenko, E.S., and Novichkov, V.Yu., Properties of Niobium Coatings Electrodeposited from Fluoride Melts, Elektrokhimiya, 1996, vol. 32, no.12, pp. 1466–1471.
Kolosov, V.N. and Shevyrev, A.A., Effect of Heat Treatment on the Structure and Properties of Superconducting Nb and Nb3Sn Electrodeposits, Neorg. Mater., 2004, vol. 40, no.3, pp. 286–291 [Inorg. Mater. (Engl. Transl.), vol. 40, no. 3, pp. 235–240].
Vonsovskii, S.V., Izyumov, Yu.A., and Kurmaev, E.Z., Sverkhprovodimost' perekhodnykh metallov, ikh splavov i soedinenii (Superconductivity of Transition Metals and Their Alloys and Compounds), Moscow: Nauka, 1977.
Metallurgy of Superconducting Materials, Luhman, T. and Dew-Hughes, D., Eds., New York: Academic, 1979. Translated under the title Metallurgiya sverkhprovo-dyashchikh materialov, Moscow: Metallurgiya, 1984.
Tablitsy fizicheskikh velichin (Tables of Physical Quantities), Kikoin, I.K., Ed., Moscow: Atomizdat, 1976.
Spravochnik po fiziko-tekhnicheskim osnovam kriogeniki (Physicochemical Principles of Cryogenics), Malkov, M.P., Ed., Moscow: Energoatomizdat, 1985.
Synthesis, Characterization, and Application of Superconducting Niobium Stannide (Nb3Sn), RCA Rev., 1964, vol. 25, no.3. Translated under the title Sverkhprovo-dyashchee soedinenie niobii-olovo, Moscow: Metallurgiya, 1970.
Bussiere, J.F., Welsh, D.O., and Suenaga, M., Young's Modulus of Polycrystalline Nb3Sn between 4.2 and 300 K, J. Appl. Phys., 1980, vol. 51, no.2, pp. 1030–1033.
Kolosov, V.N. and Novichkov, V.Yu., Zero-Current Deposition of Superconducting Nb3Sn Coatings from Molten Salts, Neorg. Mater., 2003, vol. 39, no.5, pp. 583–590 [Inorg. Mater. (Engl. Transl.), vol. 39, no. 5, pp. 485–491].
Baraboshkin, A.N., Elektrokristallizatsiya metallov iz rasplavlennykh solei (Electrocrystallization of Metals from Molten Salts), Moscow: Nauka, 1976.
Kolosov, V.N., Karpenko, O.A., Gel', R.P., et al., Electrodeposition of High-Purity Molybdenum Coatings on Nickel, Neorg. Mater., 2001, vol. 37, no.12, pp. 1480–1487 [Inorg. Mater. (Engl. Transl.), vol. 37, no. 12, pp. 1263–1269].
Kolosov, V.N., Matychenko, E.S., Orlov, V.M., and Belyaevskii, A.T., Diffusion-Coating of Nickel with Tantalum in Chloride-Fluoride-Tantalate Melts, Zh. Prikl. Khim. (S.-Peterburg), 2001, vol. 34, no.9, pp. 1452–1456.
Bashilov, V.A., Zhimerin, D.G., Kunakov, Ya.N., and Mel'nikov, V.N., Superconducting Niobium Stannide Tape, in Sverkhprovodyashchie materialy (Superconducting Materials), Moscow: Nauka, 1974, pp. 76–80.
Carlson, R.V., Barlett, R.J., Newkirk, L.R., and Valencia, F.A., Critical Current Measurement of CVD Prepared Nb3Ge Containing Various Amount of Second Phase (Nb5Ge3) Materials, IEEE Trans. Magn., 1977, no. 1, pp. 648–650.
Author information
Authors and Affiliations
Additional information
__________
Translated from Neorganicheskie Materialy, Vol. 41, No. 9, 2005, pp. 1094–1105.
Original Russian Text Copyright © 2005 by Kolosov.
Rights and permissions
About this article
Cite this article
Kolosov, V.N. Criteria for Selecting Substrates for Nb3Sn Electrodeposition. Inorg Mater 41, 961–971 (2005). https://doi.org/10.1007/s10789-005-0246-2
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/s10789-005-0246-2